92425-84-8Relevant articles and documents
Highly diastereoselective synthesis of tertiary alcohols via intramolecular Baylis-Hillman reaction using less reactive acrylamides as activated alkenes and ketones as electrophiles
Basavaiah, Deevi,Reddy, Guddeti Chandrashekar,Lingaiah, Balthu,Naganaboina, Ram Tilak
, p. 859 - 867 (2017/01/29)
A simple and convenient protocol for highly diastereoselective intramolecular Baylis-Hillman (IBH) reaction of substrates containing less reactive acrylamides as activated alkene and ketones with α-chiral center (racemic) as electrophile components, thus
Br?nsted acid mediated N-O bond cleavage for α-amination of ketones through the aromatic nitroso aldol reaction
Ramakrishna, Isai,Sahoo, Harekrishna,Baidya, Mahiuddin
, p. 3215 - 3218 (2016/02/20)
A Br?nsted acid mediated N-O bond cleavage for α-amination of ketones has been developed through the nitroso aldol reaction of less-reactive aromatic nitroso compounds and silyl enol ethers having a disilane (-SiMe2TMS) backbone. This transform