92434-54-3Relevant academic research and scientific papers
Photochemistry of o-pyrrolylstilbenes and formation of spiro-2H-pyrroles and their rearrangement to dihydroindoles
Basaric, Nikola,Marinic, Zeljko,Sindler-Kulyk, Marija
, p. 9382 - 9392 (2006)
(Chemical Equation Presented) Excited states of stilbenylpyrroles 1a-1c deactivate by two photochemical processes: cis-trans-isomerization and hydrogen transfer of NH to the stilbene double bond. NH-transfer results in the formation of two quinone dimetha
Catalytic enantioselective C(sp3)H functionalization: Intramolecular benzylic [1,5]-hydride shift
Yu, Jie,Li, Nan,Chen, Dian-Feng,Luo, Shi-Wei
supporting information, p. 2859 - 2864 (2014/05/06)
The catalytic asymmetric [1,5]-hydride transfer/cyclization sequence involving benzylic C(sp3)H bond was established, providing tetrahydronaphthalene derivatives in moderate to high yield with up to 69% ee, by employing the copper complex of si
Palladium(0)-catalyzed arylative dearomatization of phenols
Rousseaux, Sophie,Garcia-Fortanet, Jorge,Del Aguila Sanchez, Miguel Angel,Buchwald, Stephen L.
, p. 9282 - 9285 (2011/08/04)
The palladium-catalyzed arylative dearomatization of phenols to yield spirocyclohexadienone products in good to excellent yields has been developed. Preliminary results demonstrate that the formation of the spirocyclic all-carbon quaternary center can be accomplished with high levels of enantiocontrol (up to 91% ee).
Orthogonal synthesis of isoindole and isoquinoline derivatives from organic azides
Hui, Benjamin Wei-Qiang,Chiba, Shunsuke
supporting information; experimental part, p. 729 - 732 (2009/08/12)
(Chemical Equation Presented) α-Azido carbonyl compounds bearing a 2-alkenylaryl moiety at the α-position are found to be promising precursors for synthesis of isoindole and isoquinoline derivatives via 1,3-dipolar cycloaddrtion of azides onto alkenes and fcrelectrocyclization of N-H imine intermediates, respectively.
