924658-35-5

Basic information

• Product Name: ethyl 2-(acetoxy(4-bromophenyl)methyl)acrylate
• Synonyms: ethyl 2-(acetoxy(4-bromophenyl)methyl)acrylate
• CAS NO: 924658-35-5
• Molecular Weight: 327.175
• Mol File: 924658-35-5.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: ethyl 2-(acetoxy(4-bromophenyl)methyl)acrylate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 2-(acetoxy(4-bromophenyl)methyl)acrylate(924658-35-5)
• EPA Substance Registry System: ethyl 2-(acetoxy(4-bromophenyl)methyl)acrylate(924658-35-5)

Safety Data

• Hazardous Substances Data: 924658-35-5(Hazardous Substances Data)

Upstream product

• 75-36-5 acetyl chloride 
• 1122-91-4 4-bromo-benzaldehyde 
• 140-88-5 ethyl acrylate 
• 108-24-7 acetic anhydride 

Downstream Products

• 924658-10-6 2-[(4-bromophenyl)-phenylamino-methyl]-acrylic acid ethyl ester 
• 924658-18-4 2-[(4-bromophenyl)-(4-fluoro-phenylamino)-methyl]-acrylic acid ethyl ester 
• 1174930-60-9 C₁₄H₁₁BrN₂O 
• 1174930-55-2 C₁₆H₁₆BrNO₃ 
• 1400358-59-9 C₁₉H₁₃BrN₂O 
• 1400358-41-9 C₂₁H₁₈BrNO₃ 
• 1621485-82-2 6-(4-bromobenzyl)-1,3-dimethyl-1,2,3,4,7,8-hexahydropyrido[2,3-d]pyrimidine-2,4,7-trione 

Relevant articles and documents

Methylsulfenylation of Electrophilic Carbon Atoms: Reaction Development, Scope, and Mechanism

An innovative method for the methylsulfenylation of electrophilic carbons was explored. Cheap and commercially available dimethyl sulfoxide (DMSO) was used as a source of the –SCH3 group. Chalcone, dibenzylideneacetone, and Morita–Baylis–Hillma

On the development of a nucleophilic methylthiolation methodology

Methylthiolation reactions are usually explored to access organosulfur compounds using methanethiol, an extremely flammable and toxic compound. Herein, methylthiomethyl esters were successfully applied as novel methylthiolation reagents in a low cost, transition-metal-free methodology. These reagents allowed the methylthiolation of a wide scope of chalcones, acyl ester derivatives and Morita-Baylis-Hillman acetates with good group tolerance, affording the methylthiolated products in moderate to excellent yields. The reaction mechanism was investigated through several control experiments, as well as by theoretical calculations employing Density Functional Theory. The results strongly support that a sulfurane and a sulfonium ylide appear as key intermediates and that a Pummerer type rearrangement is also crucial for the formation of this novel reagent. Furthermore, the methylthiolation mechanism is likely to proceed through the nucleophilic attack of the reagent, followed by an entropically favoured step involving the acetate attack to the positively charged species, then releasing the product. This journal is

Fe(III)-Catalyzed Hydroallylation of Unactivated Alkenes with Morita-Baylis-Hillman Adducts

An Fe(III)-catalyzed hydroallylation of unactivated alkenes with Morita-Baylis-Hillman adducts via an Fe-catalyzed process is described. A variety of alkenes, including mono-, di-, and trisubstituted alkenes, could all smoothly convert to structural diver