924882-07-5

Basic information

• Product Name: 1,1-Cyclopropanedicarboxylic acid, 2-[(1E)-2-phenylethenyl]-, 1,1-diethyl ester
• CAS NO: 924882-07-5
• Molecular Formula: C17H20O4
• Molecular Weight: 288.343
• Mol File: 924882-07-5.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: 1,1-Cyclopropanedicarboxylic acid, 2-[(1E)-2-phenylethenyl]-, 1,1-diethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1-Cyclopropanedicarboxylic acid, 2-[(1E)-2-phenylethenyl]-, 1,1-diethyl ester(924882-07-5)
• EPA Substance Registry System: 1,1-Cyclopropanedicarboxylic acid, 2-[(1E)-2-phenylethenyl]-, 1,1-diethyl ester(924882-07-5)

Safety Data

• Hazardous Substances Data: 924882-07-5(Hazardous Substances Data)

Upstream product

• 25364-76-5 1,3-diethyl 2-[(2E)-3-phenylprop-2-en-1-ylidene]propanedioate 
• 1774-47-6 trimethylsulfoxonium iodide 
• 100-39-0 benzyl bromide 
• 202336-20-7 diethyl 2-(hydroxymethyl)cyclopropane-1,1-dicarboxylate 
• 13353-23-6 ethyl (±)-4,5-epoxy-2-(ethoxycarbonyl)pentanoate 
• 2049-80-1 (2-propenyl)propanedioic acid diethyl ester 
• 55502-72-2 diethyl 2-formylcyclopropane-1,1-dicarboxylate 
• 1449-46-3 benzyltriphenylphosphonium bromide 
• 2181-42-2 trimethylsulphonium iodide 
• 14371-10-9 (E)-3-phenylpropenal 
• 105-53-3 diethyl malonate 

Relevant articles and documents

Functionalized Cyclopropanes as Versatile Intermediates for the Diversity-Oriented Synthesis of γ-Lactones, γ-Lactams and δ-Lactams

A two-step procedure for the preparation of cyclopropanecarboxaldehyde-1,1-diester from a γ,δ-epoxyester and its synthetic versatility are described herein. The epoxide ring-opening/cyclopropanation process occurs in the presence of Mg(ClO 4) 2under heating, resulting in cyclopropanemethanol-1,1-diester in 65% yield. A mild TEMPO-mediated oxidation of this substrate readily generated the corresponding aldehyde in 75% yield, which was applied in the one-pot synthesis of four cyclopropylidene-γ-lactams and three δ-lactams. In addition, vinylcyclopropanes were obtained through the Wittig reaction of the aldehyde with phosphonium salts and used as precursors for tetrahydrofurans.

Lewis Acid-Catalyzed [3+3] Annulation of Donor-Acceptor Cyclopropanes and Indonyl Alcohols: One Step Synthesis of Substituted Carbazoles with Promising Photophysical Properties

A highly efficient protocol to access carbazole from donor-acceptor cyclopropane and indonyl alcohol via [3+3] annulation in the presence of a Lewis acid has been demonstrated. This method facilitates the post functionalization of the substituted carbazol

Lewis Acid Catalyzed Formal [3+2] Cycloaddition of Donor-Acceptor Cyclopropanes and 1-Azadienes: Synthesis of Imine Functionalized Cyclopentanes and Pyrrolidine Derivatives

Lewis acid catalyzed formal [3+2] cycloadditions of 1-azadienes with donor acceptor cyclopropanes to synthesize varieties of imine functionalized cyclopentanes and pyrrolidine derivatives in moderate to high yield have been developed. Moreover, pharmaceut