92543-42-5

Basic information

• Product Name: bis(1,10-phenanthroline)(dipyrido(3,2-alpha-2'.3'-C)phenazine)ruthenium (II)
• Synonyms: bis(1,10-phenanthroline)(dipyrido(3,2-alpha-2'.3'-C)phenazine)ruthenium (II)
• CAS NO: 92543-42-5
• Molecular Formula: C42H26N8Ru+2
• Molecular Weight: 743.77944
• Mol File: 92543-42-5.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 589.1°Cat760mmHg
• Flash Point: 279.3°C
• Appearance: /
• Density: g/cm³
• CAS DataBase Reference: bis(1,10-phenanthroline)(dipyrido(3,2-alpha-2'.3'-C)phenazine)ruthenium (II)(CAS DataBase Reference)
• NIST Chemistry Reference: bis(1,10-phenanthroline)(dipyrido(3,2-alpha-2'.3'-C)phenazine)ruthenium (II)(92543-42-5)
• EPA Substance Registry System: bis(1,10-phenanthroline)(dipyrido(3,2-alpha-2'.3'-C)phenazine)ruthenium (II)(92543-42-5)

Safety Data

• Hazardous Substances Data: 92543-42-5(Hazardous Substances Data)

Upstream product

• 19535-47-8 dipyridil[3,2-a:2',3'-c]phenazine 

Relevant articles and documents

Enantiomeric Separations of Ruthenium (II) Polypyridyl Complexes Using HPLC With Cyclofructan Chiral Stationary Phases

The enantiomeric separation of 21 ruthenium (II) polypyridyl complexes was achieved with a novel class of cyclofructan-based chiral stationary phases (CSPs) in the polar organic mode. Aromatic derivatives on the chiral selectors proved to be essential for enantioselectivity. The R-napthylethyl carbamate functionalized cyclofructan 6 (LARIHC CF6-RN) column proved to be the most effective overall, while the dimethylphenyl carbamate cyclofructan 7 (LARIHC CF7-DMP) showed complementary selectivity. A combination of acid and base additives was necessary for optimal separations. The retention factor vs. acetonitrile/methanol ratio plot showed a U-shaped retention curve, indicating that different interactions take place at different polar organic solvent compositions. The separation results indicated that π-π interactions, steric effects, and hydrogen bonding contribute to the enantiomeric separation of ruthenium (II) polypyridyl complexes with cyclofructan chiral stationary phases in the polar organic mode.