92577-05-4

Upstream product

• 706-07-0 1-chloro-4-(2-nitrovinyl)benzene 
• 106-99-0 buta-1,3-diene 

Downstream Products

• 1245502-23-1 1-chloro-4-(6-bromo-6-nitrocyclohex-3-enyl)-benzene 
• 1245502-24-2 1-chloro-4-(6-chloro-6-nitrocyclohex-3-enyl)-benzene 
• 17321-87-8 trans-2--nitrocyclohexan 

Relevant academic research and scientific papers

Organocatalytic Michael addition/intramolecular Julia-Kocienski olefination for the preparation of nitrocyclohexenes

An asymmetric organocatalytic [3 + 3] annulation strategy based on a Michael addition/intramolecular Julia-Kocienski olefination sequence has been developed for the synthesis of 4-substituted-5-nitrocyclohex-1-ene compounds. The strategy is an alternative to the direct reluctant enantioselective Diels-Alder approach. The potential of the methodology has been demonstrated with a concise enantioselective formal synthesis of trandolapril.

PROCESS FOR PREPARING SUBSTITUTED 2-NITROBIPHENYLS

The present invention relates to a process for preparing substituted 2-nitrobiphenyls and to specific 2-nitrobiphenyls. The invention further relates to a process for preparing 2-aminobiphenyls from such 2-nitrobiphenyls and to a process for preparing (het)arylamides of such 2-aminobiphenyls.