92594-58-6Relevant academic research and scientific papers
Catalytic synthesis method of alpha-alkoxy p-chlorobenzyl phosphonate
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Paragraph 0030; 0031, (2017/08/25)
The invention relates to a preparation method of alpha-alkoxy p-chlorobenzyl phosphonate. The alpha-alkoxy p-chlorobenzyl phosphonate is obtained from a compound I and a compound II reacting for 0.1-10 hours at (-20)-50 DEG C under the effect of a catalys
Preparation method of alpha-alkoxy bi-chlorobenzyl phosphonate
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Paragraph 0024; 0025, (2017/08/25)
The invention relates to a preparation method of alpha-alkoxy bi-chlorobenzyl phosphonate. The alpha-alkoxy bi-chlorobenzyl phosphonate is obtained by performing reaction on a compound I and a compound II at a temperature of minus 20-150 DEG C under the a
Iron-catalyzed cross coupling of P-H/C-O bonds: Efficient synthesis of α-alkoxyphosphorus compounds
Li, Xue,Chen, Tieqiao,Saga, Yuta,Han, Li-Biao
supporting information, p. 1877 - 1880 (2016/02/05)
An efficient P-C bond-formation through iron-catalyzed cross coupling of P-H/C-O bonds is developed for the first time. This reaction proceeds efficiently to produce the corresponding valuable α-alkoxyphosphorus compounds under mild conditions with a wide generality.
A FACILE SYNTHESIS OF DIETHYL 1-ALKOXY-1-ARYLMETHANEPHOSPHONATES
Kim, Dae Young,Oh, Dong Young
, p. 859 - 864 (2007/10/02)
1-Alkoxy-1arylmethanephosphonates (3) can be prepared by the reaction of arylaldehyde acetal (2) and diethyl trimethylsilylphosphite (1) in the presence of stannic chloride under mild conditions.
