92666-21-2

Basic information

• Product Name: 1-BENZYLOXY-2-METHOXY-4-(1-PROPENYL)BENZENE
• Synonyms: BENZYLEUGENOL;BENZYL ISOEUGENOL;BENZYL ISOEUGENOL ETHER;BENZYL 2-METHOXY-4-PROPENYLPHENYL ETHER;ISOEUGENYL BENZYL ETHER;ISOEUGENOL BENZYL ETHER;FEMA 3695;FEMA 3698
• CAS NO: 92666-21-2
• Molecular Formula: C₁₇H₁₈O₂
• Molecular Weight: 254.32
• EINECS: 204-370-6
• Product Categories: Alphabetical Listings;Flavors and Fragrances;I-L
• Mol File: 92666-21-2.mol
• Article Data: 7

Chemical Properties

• Melting Point: 59-63 °C(lit.)
• Appearance: WHITE POWDER
• Density: 1.063 ± 0.06 g/cm³
• Solubility: soluble in Methanol
• Water Solubility: 5% IN 95% ETHANOL; CLEAR, COLORLESS SOLUTION
• CAS DataBase Reference: 1-BENZYLOXY-2-METHOXY-4-(1-PROPENYL)BENZENE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-BENZYLOXY-2-METHOXY-4-(1-PROPENYL)BENZENE(92666-21-2)
• EPA Substance Registry System: 1-BENZYLOXY-2-METHOXY-4-(1-PROPENYL)BENZENE(92666-21-2)

Safety Data

• WGK Germany: 3
• RTECS: CY8225000
• Hazardous Substances Data: 92666-21-2(Hazardous Substances Data)

Usage

Chemical Properties

White, crystalline solid; floral odor of the carnation type. Soluble in alcohol, ether. Combustible.

Uses

Perfumery, fixative.

Preparation

By benzylation of isoeugenol.

Upstream product

• 5932-68-3 (E)-2-methoxy-4-(1-propenyl)phenol 
• 100-39-0 benzyl bromide 
• 57371-42-3 4-allyl-1-benzyloxy-2-methoxybenzene 
• 100-44-7 benzyl chloride 
• 2426-87-1 3-methoxy-4-(phenylmethoxy)benzaldehyde 
• 1530-32-1 ethyltriphenylphosphonium bromide 
• 77-78-1 dimethyl sulfate 

Downstream Products

• 24762-60-5 1-(4-hydroxy-3-methoxyphenyl)propan-1,2-diol 
• 2785-87-7 2-methoxy-4-n-propylphenol 
• 119385-00-1 8-Benzyloxy-7-[(1R,2S)-2-(4-benzyloxy-3-methoxy-phenyl)-2-hydroxy-1-methyl-ethoxy]-6-methoxy-chromen-2-one 
• 119385-00-1 8-Benzyloxy-7-[(1R,2R)-2-(4-benzyloxy-3-methoxy-phenyl)-2-hydroxy-1-methyl-ethoxy]-6-methoxy-chromen-2-one 
• 119384-96-2 8-[(1R,2S)-2-(4-Benzyloxy-3-methoxy-phenyl)-2-hydroxy-1-methyl-ethoxy]-6-methoxy-7-methoxymethoxy-chromen-2-one 
• 119384-96-2 8-[(1R,2R)-2-(4-Benzyloxy-3-methoxy-phenyl)-2-hydroxy-1-methyl-ethoxy]-6-methoxy-7-methoxymethoxy-chromen-2-one 
• 119384-99-5 8-Benzyloxy-7-[2-(4-benzyloxy-3-methoxy-phenyl)-1-methyl-2-oxo-ethoxy]-6-methoxy-chromen-2-one 
• 119384-95-1 8-[2-(4-Benzyloxy-3-methoxy-phenyl)-1-methyl-2-oxo-ethoxy]-6-methoxy-7-methoxymethoxy-chromen-2-one 
• 1835-16-1 1-(4-(benzyloxy)-3-methoxyphenyl)-2-bromopropan-1-one 
• 2426-87-1 3-methoxy-4-(phenylmethoxy)benzaldehyde 
• 1486-53-9 4-(benzyloxy)-3-methoxybenzoic acid 
• 119384-94-0 1-(4-benzyloxy-3-methoxyphenyl)-2-bromo-1-propanol 
• 121-33-5 vanillin 
• 1230-59-7 1-benzyloxy-4-(1,2-dibromo-propyl)-2-methoxy-benzene 

Relevant articles and documents

Method for synthesizing E-methyl styrene compound

The method for preparing E-pyridyl or alkyl-substituted,bipyridine, in a solvent, in the presence of nitrogen protection, in, reaction 0 °C -50 °C in the presence of a metal nickel salt 24 - 36h, ligand and an additive is E, and the preparation method disclosed by the invention has the advantages, cheap 2,2 ’ - raw materials, easiness in obtaining 2,2 ’ - and the like. The ligand is,bipyridine or an alkyl-substituted bipyridyl compound, in the. presence of a nitrogen, protection agent, in a solvent.

E-Olefins through intramolecular radical relocation

Full control over the selectivity of carbon-carbon double-bond migrations would enable access to stereochemically defined olefins that are central to the pharmaceutical, food, fragrance, materials, and petrochemical arenas. The vast majority of double-bond migrations investigated over the past 60 years capitalize on precious-metal hydrides that are frequently associated with reversible equilibria, hydrogen scrambling, incomplete E/Z stereoselection, and/or high cost. Here, we report a fundamentally different, radical-based approach.We showcase a nonprecious, reductant-free, and atom-economical nickel (Ni)(I)-catalyzed intramolecular 1,3-hydrogen atom relocation to yield E-olefins within 3 hours at room temperature. Remote installations of E-olefins over extended distances are also demonstrated.

NOVEL 1-PHENYLMONO- OR -POLYHYDROXYPROPANE COMPOUNDS, COMPOSITIONS AND COSMETIC USES THEREOF

The present invention relates to novel compounds of formula (I) to compositions comprising same, and also to the use thereof for preventing and/or cosmetically treating the signs of aging of the skin.