92670-09-2

Upstream product

• 634-36-6 1,2,3-trimethoxybenzene 
• 56-23-5 tetrachloromethane 
• 7726-95-6 bromine 
• 10385-36-1 2,3,4-trimethoxybromobenzene 
• 91-10-1 1,3-dimethoxy-2-hydroxy-benzene 
• 77-78-1 dimethyl sulfate 

Downstream Products

• 99512-65-9 1,3-dibromo-4,5,6-trimethoxy-2-nitro-benzene 
• 92669-97-1 1,5-bis(trimethylsilyl)-2,3,4-trimethoxybenzene 
• 1314438-97-5 C₅₁H₃₈N₆O₃ 
• 860692-88-2 5-allyl-2,3,4-trimethoxybenzoic acid 
• 17345-74-3 4,5,6-tribromo-pyrogallol 
• 318235-07-3 2-eneEbelacol C 

Relevant academic research and scientific papers

Probing a hidden world of molecular self-assembly: Concentration-dependent, three-dimensional supramolecular interconversions

A terpyridine-based, concentration-dependent, facile self-assembly process is reported, resulting in two three-dimensional metallosupramolecular architectures, a bis-rhombus and a tetrahedron, which are formed using a two-dimensional, planar, tris-terpyri

Side-Chain-Directed Dispersion of MoS2 Nanosheets by V-Shaped Polyaromatic Compounds

Bulk molybdenum disulfide (MoS2) itself is virtually insoluble in common organic solvents because of the tight stacks of multiple MoS2 nanosheets. Here we report that V-shaped polyaromatic compounds with non-ionic side chains can eff

Facile catch and release of fullerenes using a photoresponsive molecular tube

A novel M2L2 molecular tube capable of binding fullerene C60 was synthesized from bispyridine ligands with embedded anthracene panels and Ag(I) hinges. Unlike previous molecular cages and capsules, this open-ended tubular host can accommodate a single molecule of various C60 derivatives with large substituents. The fullerene guest can then be released by using the ideal, noninvasive external stimulus, light.

Practical and regioselective halogenations of aromatic compounds using tetrabutylammonium peroxydisulfate

The halogenated aromatic compounds have been important intermediates for various synthetic methods. Electron-rich aromatic compounds were easily iodinated using tetrabutylammonium peroxydisulfate (1) and iodine in mild conditions with excellent yields. Bromination was achieved using 1 and bromine, and regioselective bromination of highly activated aromatic compounds was also achieved using 1 and lithium bromide in mild conditions with excellent yields. Copyright Taylor & Francis Inc.

Practical and regioselective brominations of aromatic compounds using tetrabutylammonium peroxydisulfate

Direct bromination of wide range of aromatic compounds substituted with electron donating groups such as methoxy, hydroxy, or amino groups have been achieved with high regioselectivity by the reaction with Br2 in the presence of tetrabutylammonium peroxydisulfate 1 under mild conditions in acetonitrile in excellent yields. The use of lithium bromide as a bromination reagent afforded high yields of monobromo compounds with complete regioselectivity under neutral and mild reaction conditions in acetonitrile.

Preparation of analogues of Territrem B, a potent AChE inhibitor

The synthesis of analogues of the potent acetylcholinesterase inhibitor, Territrem B, was carried out starting from the naturally occurring jujubogenin glycosides. Dihydrojujubogenin-2-en-1-one (1), a dammarane derivative that possesses a skeleton and pharmacophore partially similar to those of Territrem B, was synthesized via three different paths. The derivative 21, which contains two potential pharmacophores, was also synthesized. The anti-AChE activity of the analogues was measured. The aromatic ring moiety seemed to be less important when compared with the 2-en-1-one pharmacophore. (C) 2000 Elsevier Science Ltd.

Regioselectivity in the Reactions of Methoxydehydrobenzenes with Furans. Part 2. 2-Methoxyfuran and Methoxydehydrobenzenes

Acid-induced ring opening of adducts of furan and methoxydehydrobenzenes gives the naphthalenols derived from the more stable carbocation.The cycloadditions of methoxydehydrobenzenes containing a 3-methoxy group and 2-methoxyfuran are highly regiospecific

Dilithiation of Aromatic Ethers

The lithiations of anisole and all the isomeric dimethoxy- and trimethoxybenzenes with 2-5 equiv of n-butyllithium/TMEDA complex have been investigated under a variety of reaction conditions.Anisole and m-dimethoxybenzene do not undergo dilithiatian, but