92670-09-2Relevant articles and documents
Probing a hidden world of molecular self-assembly: Concentration-dependent, three-dimensional supramolecular interconversions
Lu, Xiaocun,Li, Xiaopeng,Guo, Kai,Xie, Ting-Zheng,Moorefield, Charles N.,Wesdemiotis, Chrys,Newkome, George R.
, p. 18149 - 18155 (2014)
A terpyridine-based, concentration-dependent, facile self-assembly process is reported, resulting in two three-dimensional metallosupramolecular architectures, a bis-rhombus and a tetrahedron, which are formed using a two-dimensional, planar, tris-terpyri
Facile catch and release of fullerenes using a photoresponsive molecular tube
Kishi, Norifumi,Akita, Munetaka,Kamiya, Motoshi,Hayashi, Shigehiko,Hsu, Hsiu-Fu,Yoshizawa, Michito
supporting information, p. 12976 - 12979 (2013/09/24)
A novel M2L2 molecular tube capable of binding fullerene C60 was synthesized from bispyridine ligands with embedded anthracene panels and Ag(I) hinges. Unlike previous molecular cages and capsules, this open-ended tubular host can accommodate a single molecule of various C60 derivatives with large substituents. The fullerene guest can then be released by using the ideal, noninvasive external stimulus, light.
Practical and regioselective brominations of aromatic compounds using tetrabutylammonium peroxydisulfate
Park, Min Young,Yang, Seung Gak,Jadhav, Vidyadhar,Kim, Yong Hae
, p. 4887 - 4890 (2007/10/03)
Direct bromination of wide range of aromatic compounds substituted with electron donating groups such as methoxy, hydroxy, or amino groups have been achieved with high regioselectivity by the reaction with Br2 in the presence of tetrabutylammonium peroxydisulfate 1 under mild conditions in acetonitrile in excellent yields. The use of lithium bromide as a bromination reagent afforded high yields of monobromo compounds with complete regioselectivity under neutral and mild reaction conditions in acetonitrile.