92747-34-7Relevant academic research and scientific papers
THE SYNTHESIS OF REGIO- AND STEREOSPECIFICALLY SUBSTITUTED 1,4-DIENES OR CONJUGATED ENYENES FROM INTERNAL ALKENYLDIALKYLBORANES
Hoshi, Masayuki,Masuda, Yuzuru,Nunokawa, Yutaka,Arase, Akira
, p. 1029 - 1032 (2007/10/02)
Internal alkenyldialkylboranes give regio- and stereospecifically desidgned 1,4-dienes or conjugated enyenes, bearing a substituent at the internal alkenyl carbon atom, by a coupling reaction with allyl bromide or 1-bromo-1-alkynes.
NOVEL SYNTHESIS OF INTERNAL ALKENYLDIALKYLBORANE BY THE REACTION OF 1-HALO-1-ALKENYLDIALKYLBORANE WITH GRIGNARD REAGENT.
Arase,Hoshi,Masuda
, p. 209 - 213 (2007/10/02)
To synthesize internal alkenyldialkylboranes, coupling reactions were carried out by using 1-halo-1-alkenyldialkylboranes and Grignard reagents. Hydrogen peroxide oxidation and protonolysis with acetic acid of the reaction product revealed that internal (E)-alkenyldialkylborane was formed in 60-90% yield.
