92806-40-1Relevant academic research and scientific papers
Oxidative coupling of dichloroaluminium phenolates: Highly selective synthesis of hydroxylated Bi- and tetraaryls
Sartori, Giovanni,Maggi, Raimondo,Bigi, Franca,Arienti, Attilio,Casnati, Giuseppe,Bocelli, Gabriele,Mori, Giovanni
, p. 9483 - 9494 (1992)
Dichloroaluminium phenolates 4 undergo highly selective FeCl3-promoted oxidative coupling. Variously substituted symmetric 2,2′-dihydroxy biaryls 2 are obtained in good yields and excellent selectivities. The chelation control in the final reaction products 7 promotes the chemoselectivity of the process.
