92870-52-5Relevant academic research and scientific papers
Spectroscopic studies and crystal structure of 1-(morpholino (phenyl) methyl) pyrrolidine-2,5-dione
Rajeswari,Prabhu, G. Venkatesa,Tamilvendan,Ramkumar
, p. 437 - 442 (2010)
A new mannich base 1-(morpholino(phenyl)methyl)pyrrolidine-2,5-dione formed by the direct condensation of morpholine, succinimide and benzaldehyde has been synthesized. The structure of this mannich base has been elucidated on the basis of micro elemental analysis, IR, 1H NMR, 13C NMR, UV-Visible Techniques and Mass. The crystal structure of the title compound C15 H18 N2 O3 was determined. It crystallizes in the triclinic system, space group P - 1, with a = 8.8122(13) A, b = 9.2794(14) A, c = 9.814 (3) A, α = 107.154(9)°, β = 97.936(9)°, γ = 110.197(7)°,V = 693.4(2) A3, D x = 1.314 Mg/m3. The structure was solved by the full-matrix least squares on F2 and had a refined R value of 0.0486 for 8567 observed reflections. The six membered heterocyclic ring of the morpholino moiety adopts a chair conformation. The crystal structure is stabilized by weak intermolecular C-H???O interactions that link the molecules into inversion dimers.
