928835-99-8Relevant academic research and scientific papers
Chiral neutral zirconium amidate complexes for the asymmetric hydroamination of alkenes
Wood, Mark C.,Leitch, David C.,Yeung, Charles S.,Kozak, Jennifer A.,Schafer, Laurel L.
, p. 354 - 358 (2007)
Aminations with amidates: The first C2-symmetric amidate complexes of zirconium were used for catalytic asymmetric hydroaminations of amino alkenes to prepare chiral gem-disubstituted pyrrolidines with up to 93 % ee (see scheme). The modular nature of the chiral complexes facilitates their preparation and screening as catalysts. (Chemical Equation Presented).
