92906-82-6

Basic information

• Product Name: dimethyl-(3-phenoxy-phenyl)-amine
• Synonyms: dimethyl-(3-phenoxy-phenyl)-amine
• CAS NO: 92906-82-6
• Molecular Weight: 213.279
• Mol File: 92906-82-6.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: dimethyl-(3-phenoxy-phenyl)-amine(CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl-(3-phenoxy-phenyl)-amine(92906-82-6)
• EPA Substance Registry System: dimethyl-(3-phenoxy-phenyl)-amine(92906-82-6)

Safety Data

• Hazardous Substances Data: 92906-82-6(Hazardous Substances Data)

Upstream product

• 6848-13-1 3-chloro-N,N-dimethylaniline 
• 108-95-2 phenol 
• 50-00-0 formaldehyd 
• 3586-12-7 3-phenoxyaniline 
• 591-50-4 iodobenzene 
• 99-07-0 3-Dimethylaminophenol 
• 178752-79-9 3-(N,N-dimethylamino)phenylboronic acid 
• 16518-62-0 3-bromo-N,N-dimethylaniline 

Downstream Products

• 101-84-8 diphenylether 

Relevant articles and documents

Para-Selective C-H Olefination of Aniline Derivatives via Pd/S,O-Ligand Catalysis

Herein we report a highly para-selective C-H olefination of aniline derivatives by a Pd/S,O-ligand-based catalyst. The reaction proceeds under mild reaction conditions with high efficiency and broad substrate scope, including mono-, di-, and trisubstituted tertiary, secondary, and primary anilines. The S,O-ligand is responsible for the dramatic improvements in substrate scope and the high para-selectivity observed. This methodology is operationally simple, scalable, and can be performed under aerobic conditions.

Nickel-catalyzed C-N bond reduction of aromatic and benzylic quaternary ammonium triflates

A nickel-catalyzed, efficient C-N bond reduction of aromatic and benzylic ammonium triflates has been developed using sodium isopropoxide as a reducing agent. The high efficiency, mild conditions, and good compatibility with various substituents made this method an effective supplement to the current catalytic hydrogenation reactions. Combining this reductive deamination reaction with directed aromatic functionalization reactions, a powerful strategy for regioselective functionalization of arenes was demonstrated using dialkylamine groups as traceless directing groups.

A new biarylphosphine ligand for the Pd-catalyzed synthesis of diaryl ethers under mild conditions

A new bulky biarylphosphine ligand (L8) has been developed that allows the Pd-catalyzed C-O cross-coupling of a wide range of aryl halides and phenols under milder conditions than previously possible. A direct correlation between the size of the ligand substituents in the 2′, 4′, and 6′ positions of the nonphosphine containing ring and the reactivity of the derived catalyst system was observed. Specifically, the rate of coupling increased with the size of these substituents.