92916-02-4

Basic information

• Product Name: (+/-)-3-(p-chlorophenyl)butan-2-one
• CAS NO: 92916-02-4
• Molecular Weight: 182.65
• Mol File: 92916-02-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (+/-)-3-(p-chlorophenyl)butan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-3-(p-chlorophenyl)butan-2-one(92916-02-4)
• EPA Substance Registry System: (+/-)-3-(p-chlorophenyl)butan-2-one(92916-02-4)

Safety Data

• Hazardous Substances Data: 92916-02-4(Hazardous Substances Data)

Upstream product

• 99187-99-2 2-(4-chlorophenyl)butane-2,3-diol 
• 1679-18-1 4-Chlorophenylboronic acid 
• 4091-39-8 3-chloro-2-butanone 
• 5586-88-9 1-(4-chlorophenyl)propan-2-one 
• 74-88-4 methyl iodide 
• 6213-85-0 Methyl 4-brosylate 

Downstream Products

• 63099-43-4 Trifluoro-methanesulfonic acid (Z)-2-(4-chloro-phenyl)-1-methyl-propenyl ester 
• 63099-37-6 Trifluoro-methanesulfonic acid (E)-2-(4-chloro-phenyl)-1-methyl-propenyl ester 
• 21900-15-2 N-Ethyl-2-(p-chlorphenyl)-3-butylamin 
• 1949-63-9 2-(4-Chloro-phenyl)-N-methyl-propionamide 
• 92520-15-5 N-[1-(4-chlorophenyl)ethyl]acetamide 
• 91633-32-8 1-azido-1-(p-chlorophenyl)ethane 
• 88927-60-0 Trifluoro-acetic acid 1-(4-chloro-phenyl)-ethyl ester 
• 3391-10-4 1-(p-chlorophenyl)ethyl alcohol 
• 1309380-93-5 C₁₇H₁₈ClNO₄S 
• 1262155-51-0 C₂₀H₁₈ClNO₃S 
• 1309380-76-4 3-(p-chlorophenyl)-2-butanone oxime 
• 1173092-37-9 (R)-3-(p-chlorophenyl)butan-2-one 
• 19759-43-4 (S)-1-(4-chlorophenyl)ethyl acetate 
• 19759-43-4 (R)-1-(4-chlorophenyl)ethyl acetate 

Relevant articles and documents

Regioselective 1,2-Diol Rearrangement by Controlling the Loading of BF3·Et2O and Its Application to the Synthesis of Related Nor-Sesquiterene- and Sesquiterene-Type Marine Natural Products

The regiocontrolled rearrangement of 1,2-diols has been achieved by controlling the loading of BF3·Et2O. Its applicability is showcased by the divergent synthesis of austrodoral, austrodoric acid, and 8-epi-11-nordriman-9-one, as well as a formal synthesis of siphonodictyal B and liphagal. A new light is shed on piancol-type rearrangements that will be useful in diversity-oriented synthesis of related natural products.

Origin of regioselectivity in the reactions of nitronate and enolate ambident anions

The reactions of nitronates of ring-substituted phenylnitromethanes and enolates of ring-substituted 1-phenyl-2-propanones with MeOBs gave exclusively the O-methylated and C-methylated products, respectively. DFT calculations suggested that two factors, n

Ni-catalyzed mild arylation of α-halocarbonyl compounds with arylboronic acids

A simple yet powerful Ni catalyst can be used to promote direct arylations of α-halocarbonyl compounds, including a range of esters, amides, and ketones, with various arylboronic acids under mild conditions. The method tolerates β-hydrogens and functional groups in the substrates and offers reactivity and selectivity profiles that are complementary to those found in the well-established Buchwald-Hartwig approach.