92964-67-5

Upstream product

• 32219-15-1 2-(2-naphthalenyloxy)benzenamine 
• 528-29-0 1,2-Dinitrobenzene 
• 135-19-3 β-naphthol 
• 244103-34-2 2-(naphthalen-2-yloxy)benzaldehyde 
• 446-52-6 2-Fluorobenzaldehyde 
• 32219-12-8 2-(2-nitrophenoxy)naphthalene 

Downstream Products

• 479669-16-4 2-(2-naphthoxy)phenyl trifluoromethanesulfonate 
• 1400883-62-6 C₂₃H₁₈O₄S 
• 1440730-11-9 2-(naphthalene-2-yloxy)phenyl pivalate 
• 243-42-5 β-brazan 
• 205-39-0 benzo[b]naphtho[1,2-d]furan 

Relevant academic research and scientific papers

Metal-free oxidative aromatization of 2-aryloxycyclohex-2-en-1-ones to 2-aryloxyphenols using DDQ/Amberlyst-15

Efficient metal-free oxidative aromatization of 2-aryloxycyclohex-2-en-1-ones was achieved by a combination of 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) and Amberlyst-15. The conditions for oxidative aromatization are mild and applicable for a variety of substrates, and Amberlyst-15 can be successfully recovered and recycled.

Synthesis of polycyclic xanthenes and furans via palladium-catalyzed cyclization of polycyclic aryltriflate esters

Palladium-catalyzed cyclization of polycyclic aromatic o-(arylmethyl)phenol triflate esters takes place with unexpected sulfur-oxygen bond cleavage to furnish polycyclic xanthenes. These are the first examples of Pd-catalyzed cross-coupling of aryl triflate esters with arenes to form diaryl ethers. In contrast, analogous palladium-catalyzed cyclization of polycyclic o-(aryloxy)phenol triflate esters proceeds via a mechanism that involves conventional carbon-oxygen bond cleavage to furnish diaryl furans.