93012-47-6

Basic information

• Product Name: 1-(2-hydroxy-6-methoxyphenyl)-3-phenylpropane-1,3-dione
• Synonyms: 1-(2-hydroxy-6-methoxyphenyl)-3-phenylpropane-1,3-dione
• CAS NO: 93012-47-6
• Molecular Weight: 270.285
• Mol File: 93012-47-6.mol

Chemical Properties

• CAS DataBase Reference: 1-(2-hydroxy-6-methoxyphenyl)-3-phenylpropane-1,3-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-hydroxy-6-methoxyphenyl)-3-phenylpropane-1,3-dione(93012-47-6)
• EPA Substance Registry System: 1-(2-hydroxy-6-methoxyphenyl)-3-phenylpropane-1,3-dione(93012-47-6)

Safety Data

• Hazardous Substances Data: 93012-47-6(Hazardous Substances Data)

Upstream product

• 703-23-1 2'-hydroxy-6'-methoxyacetophenone 
• 93-89-0 benzoic acid ethyl ester 
• 98-88-4 benzoyl chloride 
• 699-83-2 2,6-dihydroxylacetophenone 
• 118021-63-9 1-(2-benzoyloxy-6-methoxy-phenyl)-ethanone 
• 93-97-0 benzoic acid anhydride 

Downstream Products

• 136764-56-2 1a,7a-Dihydro-6-methoxy-1a-phenyl-7H-oxireno<1>benzopyran-7-one 
• 42079-78-7 5-methoxyflavone 

Relevant articles and documents

Transition-Metal-Free Photoinduced Intramolecular Annulation of 2,3-Di(hetero)arylchromen-4-one

An efficient transition-metal-free photoinduced intracyclization of 4H-chromen-4-ones in EtOH-H2O (7:1, v/v) at ambient temperature for the construction of complicated fused-ring heteroaromatics is established. The reaction proceeds smoothly without requiring any catalysts/additives.

Epoxidation of Flavones by Dimethyldioxirane

The synthesis of epoxides 2 by epoxidation of flavones 1 with isolated dimethyldioxirane (as acetone solution) at subambient temperatures is reported.These labile epoxides were isolated and completely characterized by UV, IR, 1H and 13C NMR, MS, and C,H analyses.Warming to room temperature led to rearrangement to afford quantitatively the 3-hydroxyflavones 3b,h,i,n.Treatment of the epoxides 2b,f with methanol led to the 3-hydroxy-2-methoxyflavanones 4b,f, as a mixture of cis and trans isomers.