93043-89-1Relevant academic research and scientific papers
Application of pyranoside phosphite-pyridine ligands to enantioselective metal-catalyzed allylic substitutions and conjugate 1,4-additions
Lega, Matteo,Margalef, Jessica,Ruffo, Francesco,Pamies, Oscar,Dieguez, Montserrat
, p. 995 - 1000 (2013/09/23)
A series of glucopyranoside phosphite-pyridine ligands have been applied in the metal-catalyzed allylic substitution and conjugate 1,4-addition reactions of several substrate types. We have been able to identify ligands that provided promising enantioselectivities in the Pd-catalyzed intermolecular allylic substitution of cyclic substrates (ee's up to 86%) and desymmetrization (ee's up to 94%) and in the Cu-catalyzed conjugate addition of challenging aliphatic enones (ee's up to 90%).
MOLIBDENUM HEXACARBONYL AS A THIOPHILIC METAL REAGENT: DESULFENYLATIVE ALLYLATION USING ALLYLIC SULFIDES
Masuyama, Yoshiro,Yamada, Kohji,Kurusu, Yasuhiko
, p. 443 - 444 (2007/10/02)
Molybdenum hexacarbonyl is a useful reagent for desulfenylative allylation of carbon nucleophiles with allylic sulfides.
