930578-76-0Relevant academic research and scientific papers
Self-assembled carboxylate complexes of zinc, nickel and copper
Deka, Kaustavmoni,Barooah, Nilotpal,Sarma, Rupam Jyoti,Baruah, Jubaraj B.
, p. 44 - 49 (2007)
A metallo-organic hybrid acid namely tetra-aquo bis-4-carboxy-N-phthaloylglycinato zinc(II) dihydrate is prepared and characterised. In this complex the hydrogen bonding by free carboxylic acid group and π-π interactions between the rings in crystal lattice contributes to the formation of self-assembled structure. A monomeric nickel complex from 2-carbomethoxy benzoic acid (L2H) and pyridine [Ni(L2)(py)3(H2O)2]L2 is prepared (where py = pyridine). This complex has ionic as well as monodentate carboxylates. It forms self-assembly by C-H?π as well as hydrogen-bonding interactions. The 2-carbomethoxy benzoic acid (L2H) forms dimeric copper complex [Cu2(L2)4(H2O)2]2H2O which has an extended chain structure through hydrogen-bond interactions.
