93085-47-3

Basic information

• Product Name: 3-Buten-1-amine, 4-phenyl-, (Z)-
• CAS NO: 93085-47-3
• Molecular Formula: C10H13N
• Molecular Weight: 147.22
• Mol File: 93085-47-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-Buten-1-amine, 4-phenyl-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Buten-1-amine, 4-phenyl-, (Z)-(93085-47-3)
• EPA Substance Registry System: 3-Buten-1-amine, 4-phenyl-, (Z)-(93085-47-3)

Safety Data

• Hazardous Substances Data: 93085-47-3(Hazardous Substances Data)

Upstream product

• 143741-67-7 N-(4-phenyl-3-butenyl)phthalimide 
• 100-52-7 benzaldehyde 
• 89996-01-0 (3-aminopropyl)(triphenyl)phosphonium bromide 

Downstream Products

• 1229026-39-4 (Z)-2-(4-phenyl-3-butenyl)-2H-indazole-3-carbonitrile N-oxide 
• 428453-46-7 N-(4-nitrophenylsulfonyl)-(Z)-4-phenyl-but-3-enylamine 
• 126376-92-9 N-(4-phenyl-3-cis-butenyl)-1H-imidazole-4-ethanamine 
• 428453-34-3 (Z)-4-methyl-N-(4-phenylbut-3-en-1-yl)benzenesulfonamide 

Relevant articles and documents

Convenient route to primary (Z)-allyl amines and homologs

A convenient two-step procedure for the synthesis of primary (Z)-allyl amines, (Z)-homoallyl amines [(Z)-but-3-enylamines], and (Z)-pent-4-enylamines using the Wittig reaction was achieved. The use of nonstabilized ylides from triphenylphosphonium salt, potassium salt, and apolar solvent produced (Z/E)-geometric isomer ratios generally greater than 1.6. The amine moiety was masked using a phtalimide group that was removed successfully in the last step of the process in two different conditions, NH2NH2/EtOH/rt or CH3NH2/EtOH/rt. However, in some cases, reduction of the C = C double bond in the deprotection with hydrazine was concomitantly observed. Copyright Taylor & Francis Group, LLC.