Tetrahedron Letters p. 3493 - 3496 (1984)
Update date:2022-08-02
Topics:
Mora, J.
Costa, A.
Anions generated from trialkylsilyl ethers of methyl ketoximes (1) undergo anionic rearrangement with 1,4 migration of the silyl group.After protonation, the resulting α-trialkylsilyl ketoximes (2), suffer thermal rearrangement with 1,4 migration of the silyl group from carbon to oxygen.
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