93156-98-0Relevant academic research and scientific papers
Reactions of benzazole-2-thiones with 3,5-di-tert-butyl-4-hydroxybenzyl acetate
Tagasheva,Gataullina,Zaripova,Bukharov,Nugumanova,Deberdeev,Voronina, Yu. K.
, p. 22 - 28 (2017/07/07)
The benzylation of benzothiazole(oxazole, imidazole)-2-thiones with 3,5-di-tert-butyl-4-hydroxybenzyl acetate involves either the sulfur or nitrogen atom depending on the reaction conditions. The S- and N-benzylation products of benzazole-2-thiones are kinetically and thermodynamically controlled products, respectively. The use of 3,5-di-tert-butyl-4-hydroxy-benzyl acetate allows sterically hindered hydroxybenzyl derivatives of benzаzole-2-thiones to be generally synthesized under milder conditions than in known methods of their synthesis.
Reaction of Tetramethylcalix[4]resorcinolarene with 3,5-Di-tert-butyl-4- hydroxybenzyl Acetate
Bukharov,Nugumanova,Mukmeneva,Teregulova,Burilov,Pudovik,Nikolaeva,Kasymova,Konovalov
, p. 689 - 691 (2007/10/03)
Upper-rim modification of tetramethylcarix[4]resorcinolarene with 3,5-di-tert-butyl-4-hydroxybenzyl fragments is accompanied by unusual decomposition of the macroring in the modified product with formation of 2,4,6-tris(3,5-di-tert-butyl-4-hydroxybenzyl)r
