93214-66-5

Basic information

• Product Name: 2,5-Cyclohexadien-1-one, 4-(1,1-dimethylethoxy)-2,6-bis(1,1-dimethylethyl)-4-[[(1,1-dimethylethyl) oxidoimino]methyl]-
• CAS NO: 93214-66-5
• Molecular Formula: C23H39NO3
• Molecular Weight: 377.568
• Mol File: 93214-66-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,5-Cyclohexadien-1-one, 4-(1,1-dimethylethoxy)-2,6-bis(1,1-dimethylethyl)-4-[[(1,1-dimethylethyl) oxidoimino]methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5-Cyclohexadien-1-one, 4-(1,1-dimethylethoxy)-2,6-bis(1,1-dimethylethyl)-4-[[(1,1-dimethylethyl) oxidoimino]methyl]-(93214-66-5)
• EPA Substance Registry System: 2,5-Cyclohexadien-1-one, 4-(1,1-dimethylethoxy)-2,6-bis(1,1-dimethylethyl)-4-[[(1,1-dimethylethyl) oxidoimino]methyl]-(93214-66-5)

Safety Data

• Hazardous Substances Data: 93214-66-5(Hazardous Substances Data)

Upstream product

• 29211-05-0 α-(3,5-Di-tert-butyl-5-hydroxyphenyl)-N-tert-butyl-nitron 
• 1876-22-8 di-tert-butyl diperoxyoxalate 
• 54749-42-7 2,6-Di-tert-butyl-(N-tert-butylnitrono)phenoxyl 

Downstream Products

• 123-39-7 N-Methylformamide 
• 2425-74-3 t-butylformamide 
• 27701-01-5 methyl N-tert-butylcarbamate 
• 7330-85-0 4-tert-Butoxy-2,6-di-tert-butylphenol 
• 93245-39-7 C₂₄H₄₀Cl₂NO₃ 

Relevant articles and documents

Reactions of the 2,6-Di-tert-butyl-4-(N-tert-butylnitrono)-phenoxyl Radical

The title compound, a phenoxyl radical containing a nitrono group, reacts with alcohols and tert-butylhydroperoxide yielding phenol and products of secondary solvent reactions.The reactions with lead tetraacetate, tert.-butoxy and 2-cyanoisopropyl radicals give high yields of cyclohexadienone adducts (6, 7 and 10) containing unchanged nitrono function.The reaction with dibenzoylperoxide, however, leads to the modification of the nitrono group yielding the N-benzoyloxycarboxamide (8).In the acidic decomposition of the tert-butoxy radical adduct we suggest a nitrenium ion (16) as an intermediate.