932395-39-6

Basic information

• Product Name: (Z)-(((3,3,3-trifluoroprop-1-en-1-yl)oxy)methyl)benzene
• Synonyms: (Z)-(((3,3,3-trifluoroprop-1-en-1-yl)oxy)methyl)benzene
• CAS NO: 932395-39-6
• Molecular Weight: 202.176
• Mol File: 932395-39-6.mol

Chemical Properties

• CAS DataBase Reference: (Z)-(((3,3,3-trifluoroprop-1-en-1-yl)oxy)methyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-(((3,3,3-trifluoroprop-1-en-1-yl)oxy)methyl)benzene(932395-39-6)
• EPA Substance Registry System: (Z)-(((3,3,3-trifluoroprop-1-en-1-yl)oxy)methyl)benzene(932395-39-6)

Safety Data

• Hazardous Substances Data: 932395-39-6(Hazardous Substances Data)

Upstream product

• 100-51-6 benzyl alcohol 
• 102687-65-0 trans-1-chloro-3,3,3-trifluoropropene 
• 99728-16-2 (Z)-1-chloro-3,3,3-trifluoro-1-propene 
• 2730-62-3 2-chloro-1,1,1-trifluoropropene 

Downstream Products

• 460-40-2 3,3,3-trifluoropropanal 
• 100-51-6 benzyl alcohol 
• 103-50-4 dibenzyl ether 

Relevant articles and documents

Applications of 2-Chloro-3,3,3-trifluoroprop-1-ene (HCFO-1233xf): A Rapid Entry to Various β-Substituted-trifluoromethyl-ethenes

An efficient base-promoted reaction of O-, N-, and S-nucleophiles with 2-chloro-3,3,3-trifluoprop-1-ene (HCFO-1233xf) is described providing access to various β-substituted-trifluoromethyl-ethenes under mild reaction conditions. Mechanistic investigations shed some light on the regio-, chemo-, and stereoselectivities observed. The olefins prepared represent attractive intermediates in chemical discovery: Some applications include their conversion to pyrrolidines via a [3 + 2] dipolar cycloaddition reaction. These weakly basic amines represent novel synthons that could be readily elaborated through a range of reactions.

Reaction of substituted phenols and alcohols with (E)-1-chloro-3,3,3-trifluoropropene (HFCO-1233zd)

Simple and convenient one-pot procedures for the preparation of ArOCH=CHCF3, ROCH=CHCF3 and CF3CH=CHOArOCH = CHCF3 starting from the industrial product HFCO-1233zd (CF3CH=CHCl) are presented. These syntheses involve the reaction of 1233zd with phenols and alcohols in the presence of potassium hydroxide in DMF or pyridine solvent at elevated temperatures.

METHOD FOR PRODUCING 3,3,3-TRIFLUOROPROPANOL

PROBLEM TO BE SOLVED: To provide a method for producing 3,3,3-trifluoropropanol efficiently on an industrial scale. SOLUTION: 3,3,3-trifluoropropanol is produced by the reaction between benzyl vinyl ether represented by the following formula [where R is a phenyl group, or a phenyl group having a substituent represented by R1 (where R1 is an alkyl group, an alkoxy group, a halogen atom or a nitro group)] and hydrogen (H2) in the presence of a palladium catalyst. SELECTED DRAWING: None COPYRIGHT: (C)2018,JPOandINPIT

PROCESS FOR PRODUCING 3,3,3-TRIFLUOROPROPIONIC ACID

A benzyl vinyl ether represented by the following formula is hydrolyzed in the presence of a catalyst selected among Arrhenius acids and Lewis acids to obtain 3,3,3-trifluoropropionaldehyde. Subsequently, the 3,3,3-trifluoropropionaldehyde is oxidized with an oxidizing agent. Thus, 3,3,3-trifluoropropionic acid can be more advantageously produced than in conventional techniques from an inexpensive starting material.

PROCESS FOR PRODUCING 3,3,3-TRIFLUOROPROPIONALDEHYDE

A process for producing 3,3,3-trifluoropropionaldehyde which comprises hydrolyzing a benzyl vinyl ether represented by the formula [1]: (wherein R represents phenyl or phenyl substituted by R1 (R1 represents a member selected among alkyl, alkoxy, halogeno, and nitro)) in the presence of a catalyst selected among Arrhenius acids and Lewis acids.