93250-28-3Relevant academic research and scientific papers
Trans dialkoxylation of cyclic alkenes: A Prevost-type reaction
Schauble, J. Herman,Trauffer, Edward A.,Deshpande, Prashant P.,Evans, Robert D.
, p. 1333 - 1339 (2007/10/03)
Reaction of anhydrous silver perchlorate, sym-collidine, and iodine (2:1:1 molar ratio) with cyclic alkenes and an excess of an alcohol in CH 2Cl2 affords trans-1,2-dialkoxycycloalkanes in high yields and purity. The reaction occurs via initial formation of the trans-iodoethers, which undergo Ag-assisted iodide abstraction to give the trans-diethers. Georg Thieme Verlag Stuttgart.
MERCURY(II) OXIDE/TETRAFLUOROBORIC ACIDPROMOTED VICINAL HYDROXY- AND ALKOXYLATION OF ALKENES
Barluenga, Jose,Alonso-Cires, Luisa,Campos, Pedro J.,Asensio, Gregorio
, p. 2563 - 2568 (2007/10/02)
The reaction of alkenes with mercury(II) oxide/tetrafluoroboric acid and alcohols or water involves reduction to Hg(O) and vicinal diethers or diols are produced in good yields.Olefins bearing benzylic hydrogens in an α position lead to cinnamyl ethers.Mechanisms are proposed to account for the products and their stereochemistry.
