93273-86-0

Basic information

• Product Name: (-)-menthyl-2-benzoylamoniacetate
• Synonyms: (-)-menthyl-2-benzoylamoniacetate
• CAS NO: 93273-86-0
• Molecular Weight: 317.428
• Mol File: 93273-86-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (-)-menthyl-2-benzoylamoniacetate(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-menthyl-2-benzoylamoniacetate(93273-86-0)
• EPA Substance Registry System: (-)-menthyl-2-benzoylamoniacetate(93273-86-0)

Safety Data

• Hazardous Substances Data: 93273-86-0(Hazardous Substances Data)

Upstream product

• 2216-51-5 (-)-menthol 
• 63254-60-4 (1R,2S,5R)-2-isopropyl-5-methylcyclohexyl 2-aminoacetate 
• 98-88-4 benzoyl chloride 
• 495-69-2 Hippuric Acid 

Downstream Products

• 101694-79-5 (-)-menthyl (1'R,2S)-2-benzoylamino-2-(4-oxotetrahydrothiopyran-3-yl)acetate 
• 101694-82-0 (-)-menthyl (1'S,2R)-2-benzoylamino-2-(2-oxocyclohexyl)acetate 
• 101649-92-7 (-)-menthyl (1'R,2S)-2-benzoylamino-2-(2-oxocyclohexyl)acetate 
• 157401-62-2 (2S,4S)-4-Benzoyloxy-pyrrolidine-2-carboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester 
• 101649-84-7 (-)-menthyl 2-benzoylamino-2-bromoacetate 
• 157401-61-1 N-Benzoyl-2(S)-(2-propenyl)glycin-(1R,2S,5R)-menthylester 

Relevant articles and documents

SYNTHESIS OF DIASTEREO- AND ENANTIOMERICALLY PURE α-AMINO-γ-OXO ACID ESTERS BY REACTION OF ACYLIMINOACETATES WITH ENAMINES DERIVED FROM 6-MEMBERED KETONES

A new efficient diastereo- and enantioselective synthesis of α-amino-γ-oxo acid esters by reaction of acyliminoacetates with enamines is described.By employing the concept of double stereodifferentiation, complete asymmetric induction (de=ee >/= 99.9 percent) for the C-C bond formation is obtained.Desulphurization of a sulphur containing product leads to the corresponding acyclic amino acid derivatives.The virtually complete anti-diastereo- and enantioselectivities are interpreted by a Diels-Alder like transition state.