93367-11-4

Basic information

• Product Name: Oxirane, [(1S)-1-(phenylmethoxy)ethyl]-, (2S)-
• CAS NO: 93367-11-4
• Molecular Formula: C11H14O2
• Molecular Weight: 178.231
• Mol File: 93367-11-4.mol

Chemical Properties

• CAS DataBase Reference: Oxirane, [(1S)-1-(phenylmethoxy)ethyl]-, (2S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Oxirane, [(1S)-1-(phenylmethoxy)ethyl]-, (2S)-(93367-11-4)
• EPA Substance Registry System: Oxirane, [(1S)-1-(phenylmethoxy)ethyl]-, (2S)-(93367-11-4)

Safety Data

• Hazardous Substances Data: 93367-11-4(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 93451-87-7 (S)-1-((S)-oxiran-2-yl)ethan-1-ol 
• 120695-27-4 (2S,3R)-3-Benzyloxy-2-phenylsulfanyl-butan-1-ol 
• 93774-79-9 (S)-4-((S)-1-Benzyloxy-ethyl)-2,2-dimethyl-[1,3]dioxolane 
• 85726-38-1 (2S,3S)-3-Benzyloxy-1,2-butandiol 

Downstream Products

• 102690-01-7 (2S,3S)-2-(benzyloxy)hept-6-en-3-ol 
• 159722-83-5 (2S,3S)-2-(benzyloxy)non-8-en-3-ol 
• 158705-23-8 (2S,3S,6S)-7-Benzenesulfonyl-2-benzyloxy-6-{(4R,5S,6S)-6-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-2,2,5-trimethyl-[1,3]dioxan-4-yl}-heptan-3-ol 
• 184827-43-8 (2S,3S)-2-benzyloxynon-5-yn-3-ol 
• 211919-67-4 (Z)-(2S,3S,10S)-2-Benzyloxy-10-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-undec-5-en-3-ol 
• 81408-36-8 (2S,3S)-2-O-benzyl-2,3-nonanediol 
• 201211-09-8 (2S,3S)-2-(benzyloxy)-4-(4-methylphenyl)butan-3-ol 
• 213018-02-1 (2S,3S)-3-Benzyloxy-1-(3-ethyl-phenyl)-butan-2-ol 
• 316373-81-6 (2S,3S)-3-O-benzyl-1-O-(2-phenethyl)butane-1,2,3-triol 
• 201211-11-2 (2S,3S)-2-(benzyloxy)-4-(3-ethenylphenyl)butan-3-ol 
• 201211-18-9 (2S,3S)-2-(benzyloxy)-8-phenyloctan-3-ol 
• 201211-17-8 (2S,3S)-2-(benzyloxy)-7-phenylheptan-3-ol 
• 201211-12-3 (2S,3S)-2-(benzyloxy)-4-(2-prop-1-enylphenyl)butan-3-ol 
• 201211-16-7 (2S,3S)-2-(benzyloxy)-6-(2-methylphenyl)hexan-3-ol 

Relevant articles and documents

Electrophilic Sulphenylation of Silyl Ketene Acetals Derived from 3-Hydroxyesters. Diastereoselective Synthesis of Protected Epoxyalcohols

Anti-3-Hydroxy-2-phenylsulphenyl esters are stereoselectively synthesized by reaction between silyl ketene acetals and phenyl sulphenyl chloride.Subsequent elaboration leads to protected epoxyalcohols.

PREPARATION OF O-PROTECTED (2S,3S)-1,2-EPOXY-3-BUTANOLS. ENANTIOSELECTIVE SYNTHESES OF (-)-RHODINOSE AND (+)-EPIMUSCARINE IODIDE

Reductive cleavage of (S,S)-1,2-3,4-diepoxybutane with lithium triethylborohydride, followed by protection gave O-protected (2S,3S)-1,2-epoxy-3-butanols, which were employed in chiral syntheses of (-)-rhodinose and (+)-epimuscarine iodide.