81408-36-8Relevant academic research and scientific papers
SYNTHESIS OF CHIRAL 1,2-DIOLS AND RELATED COMPOUNDS OF BIOLOGICAL ACTIVITIES VIA STEPWISE RING FISSION OF 5-ALKYL-6,8-DIOXABICYCLOOCTANE SKELETON
Masaki, Yukio,Serizawa, Yuzuru,Nagata, Kinnosuke,Oda, Hirohisa,Nagashima, Hiromu,Kaji, Kenji
, p. 231 - 234 (2007/10/02)
5-Alkyl-7-mesyloxymethyl-6,8-dioxabicyclooctanes, prepared from (+)-tartaric acid, were converted by means of an organoaluminium reagent Et2AlSPh into the pyranoid monothioacetals, which were utilized via the successive thioacetalization
ZnBr2-MEDIATED HIGHLY DIASTEREOSELECTIVE ADDITION OF GRIGNARD REAGENTS TO α-BENZYLOXY ALDEHYDES
Asami, Masatoshi,Kimura, Rieko
, p. 1221 - 1222 (2007/10/02)
α-Benzyloxy aldehydes reacted with Grignard reagents in the presence of ZnBr2 to afford vicinal syn-diol derivatives with high diastereoselectivity.
Synthesis of Inhibitors of Adenosine Deaminase. A Total Synthesis of erythro-3-(Adenin-9-yl)-2-nonanol and Its Isomers from Chiral Precursors
Baker, David C.,Hawkins, L. D.
, p. 2179 - 2184 (2007/10/02)
The synthesis of both isomers of EHNA2 ("erythrohydroxynonyladenine") from D- and L-rhamnose is described.The key intermediates, (R)- and (S)-2-(benzyloxy)propanal, derived respectively from 5-O-benzyl-D- and -L-rhamnitol, were each condensed w
