934-19-0Relevant academic research and scientific papers
Ring-expansion protocol: Preparation of synthetically versatile dihydrotropones
Do, Young-Sun,Sun, Ruiying,Kim, Hee Jin,Yeo, Jung Eun,Bae, Sung-Hee,Koo, Sangho
supporting information; experimental part, p. 917 - 920 (2009/06/20)
A ring-expansion protocol that consisted of the 1,2-addition of various enolate nucleophiles to 6-trimethylsiloxy-2- cyclohexene-1-one (1) and the NaIO4-promoted oxidative ring opening of the resulting diols 2, followed by an intramolecular Kno
Reactions of Trimethylsilyl Cyanide with Tropone, 2-Phenyltropone, and 2-Methoxytropone. Formations of 2-Cyano-1-hydroxytropylidene Derivatives
Saito, Katsuhiro,Kojima, Hisashi
, p. 1918 - 1921 (2007/10/02)
Reaction of trimethylsilyl cyanide (TMSCN) with tropone and 2-phenyltropone in the presence of a catalytic amount of zinc iodide in dichloromethane afforded silyl ethers of 7-cyano-1,3,5-cycloheptatriene-1-ol (2a) and 2-phenyl-7-cyano-1,3,5-cycloheptatrie
