934167-92-7Relevant academic research and scientific papers
Organocatalytic asymmetric hydrophosphination of nitroalkenes
Bartoli, Giuseppe,Bosco, Marcella,Carlone, Armando,Locatelli, Manuela,Mazzanti, Andrea,Sambri, Letizia,Melchiorre, Paolo
, p. 722 - 724 (2007)
The use of a bifunctional Cinchona alkaloid catalyst has provided a new organocatalytic strategy for the enantioselective addition of diphenylphosphine to a range of nitroalkenes, affording optically active β-nitrophosphines (up to 99% ee after crystallization); this organocatalytic approach, providing a direct route to a new class of potentially useful enantiopure P,N-ligands, constitutes a bridge between the two complementary areas of asymmetric catalysis: organo- and metal-catalyzed transformations. The Royal Society of Chemistry.
