93468-27-0

Upstream product

• 18407-84-6 1-methoxy-3,6-bis(trimethylsilyl)cyclohexa-1,4-diene 
• 56917-70-5 5-(trimethylsilyl)cyclohex-3-enone 
• 56917-71-6 5-trimethylsilyl-2-cyclohexanone 
• 118527-76-7 trans-3-benzyl-5-(trimethylsilyl)-cyclohexanone 

Downstream Products

• 64970-22-5 N,N-dimethyl-(6-benzyl-1-cyclohexenyl)methylamine hydrochloride 
• 93529-38-5 3-c-benzyl-2-c-dimethylaminomethyl-1-r-cyclohexanol 
• 93529-38-5 2-c-benzyl-2-t-dimethylaminomethyl-1-r-cyclohexanol 
• 93468-52-1 (1R,2R,3R)-3-Benzyl-2-dimethylaminomethyl-cyclohexanol; hydrochloride 

Relevant academic research and scientific papers

Silver(I)-catalyzed ring-contractive rearrangement: A new entry to 5-alkylidene-2-cyclopentenones

A novel silver(I)-catalyzed ring-contractive rearrangement of 5-substituted 6-diazo-2-cyclohexenones has been developed, providing a new and efficient access to 5-alkylidene-2-cyclopentenones. The AgOTf-catalyzed reaction proceeds through metal-carbenoid formation followed by endocyclic allyl [1,2] migration with excellent stereoselectivity and broad substrate scope.