935-72-8Relevant academic research and scientific papers
Organic light-emitting compound and preparation method and application thereof
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Paragraph 0051-0053; 0056, (2020/10/29)
The invention discloses an organic light-emitting compound as well as a preparation method and application thereof. The organic light-emitting compound has a structural formula shown in the specification, wherein in the structural formula, R is C6-C12 alkyl. According to the preparation method, 2-alkylpyrrolo[3,4-c]pyrrole-1-3(2H, 5H)-diketone is taken as a main body, and chromophoric groups, indole, are respectively introduced into symmetrical positions on two sides of pyrrole, and thereby the organic light-emitting compound is finally obtained. The organic light-emitting compound has a light-emitting characteristic in an organic solvent, wherein the fluorescence intensity is further improved after anions are introduced into a system; the organic light-emitting compound can be applied tothe fields of light-emitting devices, laser dyes, fluorescence sensitivity, anti-counterfeiting technologies, fluorescence imaging, biomedical analysis and the like.
Evaluating the influence of heteroatoms on the electronic properties of aryl[3,4-c]pyrroledione based copolymers
Hale, Benjamin J.,Elshobaki, Moneim,Gebhardt, Ryan,Wheeler, David,Stoffer, Jon,Tomlinson, Aimée,Chaudhary, Sumit,Jeffries-EL, Malika
, p. 85 - 92 (2016/12/26)
A donor-acceptor-type conjugated copolymer (PBDT-PPD) composed of benzodithiophene (BDT) and pyrrolopyrroledione (PPD) was synthesized using the Stille cross-coupling reaction. Using both experimental and theoretical data, the optical, electrochemical, and photovoltaic properties of PBDT-PPD were compared with those of its sulfur analog, PBDT-TPD, which is composed of BDT and thienopyrroledione (TPD). The optical bandgaps of the polymers were determined to be 1.86 and 2.20 eV, respectively. While both materials possessed similar highest occupied molecular orbital (HOMO) levels, the lowest unoccupied molecular orbital (LUMO) level for PBDT-PPD was raised relative to that of PBDT-TPD. Devices incorporating PBDT-PPD had a higher open-circuit voltage and fill factor, yet drastically lower short-circuit current density (Jsc) than PBDT-TPD leading to a lower power conversion efficiency (PCE). The lack of significant intramolecular charge transfer (ICT) combined with the high LUMO of PBDT-PPD resulted in poor spectral overlap with the solar spectrum, lowering Jsc. Additionally, there was poor electron injection into PCBM, which also reduced the PCE.
Nouvelle methode de synthese de pyrroles sous micro-ondes
Oussaid, Boualem,Garrigues, Bernard,Soufiaoui, Mohammed
, p. 2483 - 2485 (2007/10/02)
The dehydrogenation of pyrrolidines by manganese dioxide, under microwave irradiation, provides a mild method for the preparation of substituted pyrroles.
