93500-17-5

Upstream product

• 4551-15-9 phenylthiotrimethylsilane 
• 55557-13-6 3-methylbutyric acid trimethylsilyl ester 
• 114805-76-4 S-Phenyl 2-Iodo-3-methyl(thiobutanoate) 
• 93500-16-4 (Z)-1-methoxy-3-methyl-1-(phenylthio)but-1-ene 
• 108-98-5 thiophenol 
• 108-12-3 isopentanoyl chloride 
• 13865-50-4 methoxymethyl phenyl sulfide 
• 88738-21-0 trimethylsilane 
• 3561-67-9 bis(phenylthio)methane 
• 35453-12-4 phenyl phenylthiomethyl sulfoxide 
• 15296-86-3 1-(phenylsulfanyl)methyl phenyl sulfone 
• 120346-65-8 (trans)-3-(1'-methylethyl)-2-phenylsulfonyloxirane 
• 120346-58-9 (E)-3-methyl-1-phenylsulphonyl-1-phenylthiobut-1-ene 
• 120346-62-5 (trans)-3-(1'-methylethyl)-2-phenylsulfonyl-2-phenylthiooxirane 

Downstream Products

• 131436-08-3 r-4-cyclohexyl-c-3,4-dimethyloxetan-2-one 
• 131436-13-0 4-heptyl-3-isopropyloxetan-2-one 

Relevant academic research and scientific papers

Zeolite Beta nanoparticles assembled Cu catalysts with superior catalytic performances in the synthesis of thioesters by cross-coupling of aldehydes and disulfides

Development of the highly active and stable heterogeneous transition metal catalysts is of great importance in synthetic chemistry. Herein, zeolite Beta nanoparticles assembled Cu catalyst (Cu-Beta-Nano) with high external surface area was directly synthe

S-Acylation of aliphatic and aromatic thiols with carboxylic acids and their esters over solid acid catalysts in the gas phase at temperatures above 200 °c

Benzenethiol is reacted with acetic acid in a hydrogen stream over [(Mo6Cl8)Cl4(H2O) 2]·6H2O. Catalytic activity of the clusters appears above 200 °C, yielding S-phenyl thioacetate. The selectivity is 98% at 300 °C. Niobium, tantalum, and tungsten halide clusters with the same octahedral metal framework also catalyze the reaction. Benzoic acid and aliphatic carboxylic acids afford the corresponding S-phenyl carbothioates by reaction with benzenethiol. Aliphatic thiols are also S-acylated to yield the corresponding S-alkyl carbothioates. When carboxylic esters are applied to the reaction with benzenethiol over [(Nb6Cl12)Cl 2(H2O)4]·4H2O at 450 °C, the sterically unhindered moiety of the ester is incorporated into the products: S-phenyl thioacetate or methyl phenyl sulfide is obtained selectively. A Br?nsted acid site developed on the cluster complex by thermal activation is the active site of the catalyst. Hence, solid acids such as silica-alumina, zeolites, and heteropoly acids that are stable above 200 °C also catalyze these reactions.

Rapid and convenient thioester synthesis under phase-transfer catalysis conditions

Various thioesters were obtained through an efficient phase-transfer catalysis method, by treating several thiophenols with different acyl chlorides, in a biphasic system composed of 10% aqueous NaOH and dichloromethane in the presence of tetrabutylammonium chloride. The thiolation reaction was complete in only 5 minutes, at 0C. Taylor & Francis Group, LLC.

A New and Efficient Esterification Reaction via Mixed Anhydrides by the Promotion of a Catalytic Amount of Lewis Acid

In the presence of a catalytic amount of Lewis acid, various carboxylic esters or S-phenyl carbothioates are prepared in excellent yields by the respective reactions of equimolar amounts of silyl carboxylates and alkyl silyl ethers or phenyl silyl sulfides with 4-trifluoromethylbenzoic anhydride.

A New and Efficient Method for the Preparation of S-Phenyl Carbothioates via Mixed Anhydrides Using Active Titanium(IV) Salts

In the presence of a catalytic amount of titanium(IV) salt, various S-phenyl carbothioates are prepared in excallent yields by the reaction of nearly equimolar amounts of silyl derivatives of carboxylic acids and benzenethiols with p-trifluoromethylbenzoic anhydride.

Preparation of 2-Halogeno S-Phenyl Thioesters from 2-Phenylsulphonyl-2-phenylthiooxiranes. Crystal Structures of 2-Phenylsulphonyloxiranes

1-Phenylsulphonyl-1-phenylthioalkenes 8 are prepared with high stereoselectivity as (E) isomers in a one-pot process by reaction of phenyl phenylthiomethyl sulphone 9 with aldehydes, followed by elimination.Nucleophilic epoxidation of these alkenes with l

A Practical and Efficient Method for the Synthesis of β-Lactones

This paper describes a convenient one-step preparation of β-lactames based on the addition of thiol ester enolates to carbonyl compounds.Under the proper conditions the resulting aldolates undergo spontaneous cyclization to produce β-lactones in good to excellent yield.The new β-lactone synthesis provides access to 2-oxetanones with a variety of substituents and substitution patterns.In general, thiol ester enolates combine with carbonyl compounds to form the less sterically crowded β-lactone diasteromers, and in some cases the reaction proceeds with excellent stereoselectivity.In conjunction with the stereospecific decarboxylation of β-lactones, this chemistry also provides a very attractive approach to the synthesis of substituted alkenes.

lithium and lithium. Convenient Reagents for the Facile Conversion of Aldehydes, Ketones, and 3-Alkoxy Enones into Ketene O,S-Acetal Derivatives

The title organometalics have been found to react in the 1,2-sense with a variety of carbonyl compounds to provide O,S-acetal and ketene O,S-acetal derivatives in high yield.The β,γ-unsaturated O,S-acetals obtained via the reaction of methoxy(phenylthio)

METHOXYPHENYLTHIOTRIMETHYLSILYLMETHYLLITHIUM A CONVENIENT REAGENT FOR THE HOMOLOGATION OF CARBONYL COMPOUNDS

A facile homologation procedure for the conversion of carbonyl compounds into ketene-O,S-acetals is described.These intermediers are readily converted into ketene-O-silyl,S-acetals, thioesters, and carboxamides.