15296-86-3

Usage

Uses

Used in Organic Synthesis:
[(phenylsulfanyl)methyl]sulfonylbenzene is used as a starting material in organic synthesis for the creation of a wide range of sulfur-containing compounds. Its diverse functionality allows for the development of various chemical products.
Used in Pharmaceutical Applications:
In the pharmaceutical industry, [(phenylsulfanyl)methyl]sulfonylbenzene is used as a key intermediate in the synthesis of potential drug candidates. Its unique structural properties make it a valuable component in the development of new medications.
Used in Agrochemical Applications:
Similarly, in the agrochemical industry, [(phenylsulfanyl)methyl]sulfonylbenzene is utilized as a starting material for the synthesis of compounds with potential applications in agriculture, such as pesticides and other chemical products designed to enhance crop protection and yield.

Upstream product

• 1212-08-4 S-Phenyl benzenethiosulfonate 
• 141-52-6 sodium ethanolate 
• 5000-44-2 1-phenylsulfonyl-2-propanone 
• 3561-67-9 bis(phenylthio)methane 
• 7205-98-3 chloromethyl phenyl sulfone 
• 108-98-5 thiophenol 
• 2973-86-6 lithium thiophenoxide 
• 54384-18-8 1-phenylsulfinyl-1-phenylsulfonylmethane 
• 19169-90-5 bromomethylphenylsulfone 
• 3111-52-2 potassium thiophenolate 
• 101790-65-2 2-benzenesulfonyl-2-phenylsulfanyl-acetoacetic acid ethyl ester 

Downstream Products

• 120346-59-0 (E)-1-phenylsulphonyl-1-phenylthiohex-1-ene 
• 110890-39-6 C₁₇H₁₆O₂S₂ 
• 110890-38-5 1-phenylthio-1-phenylsulfonyl-3-cyclopentene 
• 119657-05-5 5-nitro-2-(phenylthiomethyl)benzophenone 
• 119657-06-6 3-nitro-4-(phenylthiomethyl)benzophenone 
• 882-33-7 diphenyldisulfane 
• 591-50-4 iodobenzene 
• 120346-60-3 (E)-2-phenyl-1-phenylsulphonyl-1-phenylthioethene 
• 120346-57-8 (E)-1-phenylsulphonyl-1-phenylthioprop-1-ene 
• 120346-58-9 (E)-3-methyl-1-phenylsulphonyl-1-phenylthiobut-1-ene 

Relevant academic research and scientific papers

Preparation of 2-Halogeno S-Phenyl Thioesters from 2-Phenylsulphonyl-2-phenylthiooxiranes. Crystal Structures of 2-Phenylsulphonyloxiranes

1-Phenylsulphonyl-1-phenylthioalkenes 8 are prepared with high stereoselectivity as (E) isomers in a one-pot process by reaction of phenyl phenylthiomethyl sulphone 9 with aldehydes, followed by elimination.Nucleophilic epoxidation of these alkenes with l

Experimental Charge Maps in Di-activated Carbanions: Access to Charge Demands of Primary Electron-withdrawing Functionalities

It is found that the 13C shifts of C-1 in numerous, 1,1-disubstituted ethylene derivatives, R-CH=CX2 and RCH=CXY, are predictable, relative to the unsubstituted system RCH=CH2 on the basis of additivity of the shielding contributions AX and AY.AX and AY are obtained by subtracting the shift of parent ethylene from that of C-1 in monosubstituted ethylenes CH2=CHX or CH2=CHY.This result allows an assessment of the scope of our previously proposed charge-13C relationship, equation (1), which is now applied to numerous carbanions di-activated with both identical and with different 'primary' electron-withdrawing functionalities.It is found, that the 13C shift of the carbanionic carbon is almost insensitive to the dipolar-aprotic or protic nature of the solvent, Me2SO or MeOH.The 1JCH coupling constants of the carbanionic carbon provide unequivocal evidence for the trigonal hybridization of the charged carbon in all the carbions examined, including the sulphonyl-, sulphinyl-, and cyano-stabilized systems.The ?-electron density qC at the carbanionic carbon calculated by using equation (1) for carbanions diactivated with identical groups -CHX2 provides access to the fraction of negative charge qX withdrawn by each group X: these values allow a precise prediction of qC in -CHXY, and thus, of the 13C shift of their carbanionic carbon also.The charge demand values of qX constitute a rank of electron-withdrawing capacities of primary functions: COPh, COMe, CONMe2, CO2Me, SO2R, CN, SOPh, PO(OEt)2.The values of qX as obtained from the -CHX2 anions are different but are linearly related to the qX values derived from the previously studied PhCH-X systems: they are, furthermore, related to the resonance parameters ?R- of functionalities X, in turn obtained from the PhNHX systems.

Asymmetric Microbial Oxidation of Formaldehyde Dithioacetals

Incubation of formaldehyde dithioacetals with growing cells of Corynebacterium equi IFO 3730 afforded a variety of oxidation products depending on the structure of the substrate.The products with sulfoxide moiety were optically pure and had R configuratio