93534-17-9

Usage

Physical state

Yellow solid

Odor

Distinct

Usage in synthesis

Pharmaceutical and organic compounds

Intermediate in production

Pesticides and agrochemicals

Industrial applications

Perfumes and flavorings

Investigated properties

Antitumor and antibacterial

Upstream product

• 874-42-0 2,4-dichlorobenzaldeyhde 
• 369-57-3 benzenediazonium tetrafluoroborate 
• 100-42-5 styrene 
• 13123-92-7 (2,4-dichlorophenyl)hydrazine 
• 603-33-8 triphenylbismuthane 
• 53056-20-5 2,4-dichlorophenylacetyl chloride 

Downstream Products

• 107238-79-9 2-(2,4-Dichloro-phenyl)-1-phenyl-propenone 
• 1566598-91-1 ethyl 4-(2,4-dichlorophenyl)-5-phenyl-1-(2,4,6-trichlorophenyl)-1H-pyrazole-3-carboxylate 
• 1566598-76-2 ethyl 4-(2,4-dichlorophenyl)-1,5-diphenyl-1H-pyrazole-3-carboxylate 
• 96223-58-4 1-[(4S,5R)-4-(2,4-Dichloro-phenyl)-2-oxo-5-phenyl-2λ⁴-[1,3,2]dioxathiolan-4-ylmethyl]-1H-[1,2,4]triazole 
• 96223-58-4 1-[(4S,5S)-4-(2,4-Dichloro-phenyl)-2-oxo-5-phenyl-2λ⁴-[1,3,2]dioxathiolan-4-ylmethyl]-1H-[1,2,4]triazole 
• 107710-88-3 (2R,3S)-2-(2,4-Dichloro-phenyl)-3-phenyl-1-[1,2,4]triazol-1-yl-butane-2,3-diol 
• 107680-04-6 (2R,3R)-2-(2,4-Dichloro-phenyl)-3-phenyl-1-[1,2,4]triazol-1-yl-butane-2,3-diol 
• 107680-31-9 (2S,3R)-1-(4-Chloro-phenyl)-3-(2,4-dichloro-phenyl)-2-phenyl-4-[1,2,4]triazol-1-yl-butane-2,3-diol 
• 107680-23-9 (2R,3S)-2-(2,4-Dichloro-phenyl)-3-phenyl-1-[1,2,4]triazol-1-yl-heptane-2,3-diol 
• 107659-70-1 (4S,5R)-4-(2,4-Dichloro-phenyl)-5-phenyl-4-[1,2,4]triazol-1-ylmethyl-[1,3]dioxolan-2-one 
• 107679-95-8 (4S,5R)-4-(2,4-Dichloro-phenyl)-4-imidazol-1-ylmethyl-5-phenyl-[1,3]dioxolan-2-one 
• 107659-87-0 1-[(4R,5S)-4-(2,4-Dichloro-phenyl)-5-phenyl-[1,3]dioxolan-4-ylmethyl]-1H-[1,2,4]triazole 
• 96223-35-7 (1R,2S)-2-(2,4-Dichloro-phenyl)-1-phenyl-3-[1,2,4]triazol-1-yl-propane-1,2-diol 
• 94147-49-6 2-(2,4-Dichloro-phenyl)-2-hydroxy-1-phenyl-3-[1,2,4]triazol-1-yl-propan-1-one 

Relevant academic research and scientific papers

Palladium-catalyzed synthesis of α-aryl acetophenones from styryl ethers and aryl diazonium saltsviaregioselective Heck arylation at room temperature

Preparation of α-aryl acetophenones from styryl ethers and aryldiazonium salts is described. The reaction is catalyzed by palladium acetate at room temperature in the absence of ligand and base. The developed method is highly attractive in terms of reaction conditions, substrate scope, functional group tolerance and yields. Synthetic applications of the present method are demonstrated by preparing α-aryl indoles and 3-aryl isocoumarin from styryl ethers.

Metal-free synthesis of ketones by visible-light induced aerobic oxidative radical addition of aryl hydrazines to alkenes

A green and cost-effective method has been developed for the conversion of alkenes to ketones under metal-free conditions. The reaction involves the oxidative addition of alkenes with aryl radicals, which are generated by visible-light induced aerobic oxidation of arylhydrazines. The key features of this reaction include broad substrate scope, readily available reagents and amenability to gram-scale synthesis.

Pd-catalyzed synthesis of α-aryl ketones through couplings of α-arylacetyl chlorides with triarylbismuths as multi-coupling nucleophiles

The cross-coupling reaction of α-arylacetyl chlorides with triarylbismuths was studied under Pd-catalyzed conditions. The reaction was found to be facile under the established protocol and furnished high yields of α-aryl ketones in short reaction times. T

TiCl4-catalyzed indirect anti-Markovnikov hydration of alkynes: Application to the synthesis of benzo[b]furans

(Chemical Equation Presented) An efficient methodology for the indirect anti-Markovnikov hydration of unsymmetrically substituted terminal and internal alkynes is based on TiCl4-catalyzed hydroamination reactions. Its application to ortho-alkynylhaloarenes, followed by a copper-catalyzed O-arylation, provides flexible access to substituted benzo[b]furans.