55418-35-4Relevant articles and documents
Oxidation of Silyl Enol Ethers Using 2-Sulfonyloxaziridines. Synthesis of α-Siloxy Epoxides and α-Hydroxy Carbonyl Compounds
Davis, Franklin A.,Sheppard, Aurelia C.
, p. 954 - 955 (2007/10/02)
The first isolation and detection of α-siloxy epoxides 2 in the oxidation of silyl enol ethers 1 to α-hydroxy carbonyl compounds 4 (Rubottom reaction) by 2-sulfonyloxaziridine 5 is described.Asymmetric oxidation of silyl enol ethers by (+)-(R,R)-6 affords optically active α-hydroxy carbonyl compounds.