936641-28-0

Basic information

• Product Name: cis-(2-styryl-phenyl)carbamic acid tert-butyl ester
• Synonyms: cis-(2-styryl-phenyl)carbamic acid tert-butyl ester
• CAS NO: 936641-28-0
• Molecular Weight: 295.381
• Mol File: 936641-28-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: cis-(2-styryl-phenyl)carbamic acid tert-butyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: cis-(2-styryl-phenyl)carbamic acid tert-butyl ester(936641-28-0)
• EPA Substance Registry System: cis-(2-styryl-phenyl)carbamic acid tert-butyl ester(936641-28-0)

Safety Data

• Hazardous Substances Data: 936641-28-0(Hazardous Substances Data)

Upstream product

• 24424-99-5 di-tert-butyl dicarbonate 
• 36016-38-3 tert-Butyl N-hydroxycarbamate 
• 909297-32-1 trans-(2-styrylphenyl)carbamic acid tert-butyl ester 
• 78839-75-5 2-bromo-N-(tert-butoxycarbonyl)aniline 

Downstream Products

• 936641-30-4 (Z)-2-(2-tert-butoxycarbonylamino-phenyl)-3-phenyl-acrylic acid 
• 3359-49-7 3-benzylideneoxindole 

Relevant articles and documents

Regioselective Synthesis of 2-Vinylanilines Using O-aroyloxycarba-mates by Sequential Decarboxylation/Amination/Heck Reaction

A new sequential approach for 2-vinylanilines utilizing aryl carboxylic acids as stable, inexpensive and widely available arylating reagents is described. Employing a Pd-POVs catalyst system, this protocol is not only overcoming the restriction barrier of decarboxylative coupling to ortho-substituted substrates, but also provides site-special to create new C(sp2)-N and C(sp2)-C(sp2) bonds. Mechanistic experiments suggest the cleavage of C(sp2)-COOH gives priority to C(sp2)-X bond in this reaction.