93779-85-2

Basic information

• Product Name: Benzene, 1-methyl-4-[(1-methylpropyl)thio]-, (S)-
• CAS NO: 93779-85-2
• Molecular Formula: C11H16S
• Molecular Weight: 180.314
• Mol File: 93779-85-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methyl-4-[(1-methylpropyl)thio]-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methyl-4-[(1-methylpropyl)thio]-, (S)-(93779-85-2)
• EPA Substance Registry System: Benzene, 1-methyl-4-[(1-methylpropyl)thio]-, (S)-(93779-85-2)

Safety Data

• Hazardous Substances Data: 93779-85-2(Hazardous Substances Data)

Upstream product

• 50599-13-8 S-(+)-2-butanol methanesulfonate 
• 106-45-6 para-thiocresol 
• 66194-68-1 S-(+)-methanesulfonic acid sec-butyl ester 
• 61530-30-1 (R)-sec-butyl 4-methylbenzenesulfonate 
• 10486-08-5 sodium p-thiocresolate 

Downstream Products

• 80684-99-7 1-(sec-butylsulfonyl)-4-methylbenzene 

Relevant articles and documents

Nickel-Catalyzed Enantioconvergent Reductive Hydroalkylation of Olefins with α-Heteroatom Phosphorus or Sulfur Alkyl Electrophiles

Substantial advances in enantioconvergent C(sp3)-C(sp3) bond formation reactions have been made in recent years through the use of transition-metal-catalyzed cross-coupling reactions of racemic secondary alkyl electrophiles with organometallic reagents. Herein, we report a general process for the asymmetric construction of alkyl-alkyl bonds adjacent to heteroatoms, namely, a nickel-catalyzed enantioconvergent reductive hydroalkylation of olefins with α-heteroatom phosphorus or sulfur alkyl electrophiles. Including the use of readily available olefins, this reaction has considerable advantages, such as mild reaction conditions, a broad substrate scope, and good functional group compatibility, making it a desirable alternative to traditional electrophile-nucleophile cross-coupling reactions.

Optical Stability of Carbanions Derived from Sulphoximides and Sulphilimines

Pairs of diastereomeric sulphoximides and sulphilimines of known absolute configuration have been converted into the corresponding carbanions, which have a definite optical stability.