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• 93779-85-2 (S)-(+)-2-butyl p-tolyl sulfide 
• 258356-58-0 (2S)-2-[(R)-p-tolylsulfinyl]butane 
• 10486-08-5 sodium p-thiocresolate 
• 1517-82-4 (-)-menthyl p-toluenesulfinate 
• 14195-15-4 α-(p-methylbenzenesulfonyl)propiophenone 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 74-85-1 ethene 
• 31350-99-9 1-[(1-bromoethyl)sulfonyl]-4-methylbenzene 

Relevant academic research and scientific papers

Nickel-Catalyzed Enantioconvergent Reductive Hydroalkylation of Olefins with α-Heteroatom Phosphorus or Sulfur Alkyl Electrophiles

Substantial advances in enantioconvergent C(sp3)-C(sp3) bond formation reactions have been made in recent years through the use of transition-metal-catalyzed cross-coupling reactions of racemic secondary alkyl electrophiles with organometallic reagents. Herein, we report a general process for the asymmetric construction of alkyl-alkyl bonds adjacent to heteroatoms, namely, a nickel-catalyzed enantioconvergent reductive hydroalkylation of olefins with α-heteroatom phosphorus or sulfur alkyl electrophiles. Including the use of readily available olefins, this reaction has considerable advantages, such as mild reaction conditions, a broad substrate scope, and good functional group compatibility, making it a desirable alternative to traditional electrophile-nucleophile cross-coupling reactions.

Studies on Chiral Organo-Sulfur Compounds. II. Stereochemistry of Thermal Chiral Allyl Sulfinate-Sulfone Rearrangements

A highly efficient and general synthetic route to optically active sulfinates by the stereospecific boron trifluoride etherate-catalyzed esterification of sulfinamides was developed.Dramatic solvent effects were observed in the thermal transformation of allyl sulfinate derivatives to sulfones.Heating of chiral trans- and cis-allyl sulfinates, (S)-(-)-3a,c,e and (S)-(-)-3b,d,f, in N,N-dimethylformamide at 90-120 deg C provided chiral sulfones (S)-(+)- and (R)-(-)-5,6,7 in good yields, respectively, with exceedingly high stereospecificity. Keywords - asymmetric transfer; stereospecificity; chiral allyl sulfinate; chiral allyl sulfone; boron trifluoride etherate; thermolysis

Optical Stability of Carbanions Derived from Sulphoximides and Sulphilimines

Pairs of diastereomeric sulphoximides and sulphilimines of known absolute configuration have been converted into the corresponding carbanions, which have a definite optical stability.