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[((R)-BINAP)(PMe3)PtH][BF4] is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

937792-39-7

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937792-39-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 937792-39-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 9,3,7,7,9 and 2 respectively; the second part has 2 digits, 3 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 937792-39:
(8*9)+(7*3)+(6*7)+(5*7)+(4*9)+(3*2)+(2*3)+(1*9)=227
227 % 10 = 7
So 937792-39-7 is a valid CAS Registry Number.

937792-39-7Downstream Products

937792-39-7Relevant academic research and scientific papers

Room-temperature β-H elimination in (P2P)Pt(OR) cations: Convenient synthesis of a platinum hydride

Campbell, Alison N.,Gagne, Michel R.

, p. 2788 - 2790 (2008/10/09)

In situ-generated [(BINAP)(PMe3)Pt][BF4]2 reacts with benzyl alcohol at RT to yield [(BINAP)(PMe3)Pt-H][BF 4] and benzaldehyde. This reactivity contrasts similarly ligated platinum-alky I species, which are stable to β-hydride elimination even at elevated temperatures. Protonolysis of the platinum hydride leads to a species that is readily substituted by weakly coordinating ligands (acetone, pentafluorobenzonitrile).

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