93862-80-7

Basic information

• Product Name: <(S)-N-Acetylleucyl>-<(Z)-3,4,5-triacetoxy-α,β-didehydrophenylalanyl>-<(S)-6-brom-N-<2-(3,4-diacetoxyphenyl)-2-(4-nitrophenylseleno)ethyl>tryptophanamid>
• CAS NO: 93862-80-7
• Molecular Weight: 1176.89
• Mol File: 93862-80-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: <(S)-N-Acetylleucyl>-<(Z)-3,4,5-triacetoxy-α,β-didehydrophenylalanyl>-<(S)-6-brom-N-<2-(3,4-diacetoxyphenyl)-2-(4-nitrophenylseleno)ethyl>tryptophanamid>(CAS DataBase Reference)
• NIST Chemistry Reference: <(S)-N-Acetylleucyl>-<(Z)-3,4,5-triacetoxy-α,β-didehydrophenylalanyl>-<(S)-6-brom-N-<2-(3,4-diacetoxyphenyl)-2-(4-nitrophenylseleno)ethyl>tryptophanamid>(93862-80-7)
• EPA Substance Registry System: <(S)-N-Acetylleucyl>-<(Z)-3,4,5-triacetoxy-α,β-didehydrophenylalanyl>-<(S)-6-brom-N-<2-(3,4-diacetoxyphenyl)-2-(4-nitrophenylseleno)ethyl>tryptophanamid>(93862-80-7)

Safety Data

• Hazardous Substances Data: 93862-80-7(Hazardous Substances Data)

Upstream product

• 52415-29-9 6-bromo-1H-indole 
• 57929-25-6 3,4-(diacetyloxy)benzoyl chloride 
• 6635-24-1 3,4,5-triacetoxybenzoic acid 
• 93862-77-2 3-{(S)-2-[2-((S)-2-Acetylamino-4-methyl-pentanoylamino)-2-(dimethoxy-phosphoryl)-acetylamino]-2-tert-butoxycarbonyl-ethyl}-6-bromo-indole-1-carboxylic acid tert-butyl ester 
• 93862-77-2 <(S)-N-Acetylleucyl>-<(RS)-α-(dimethoxyphosphoryl)glycyl>-<(S)-6-brom-1-(tert-butyloxycarbonyl)tryptophan-tert-butylester> 
• 100945-22-0 N-(tert-Butyloxycarbonyl)-2-(3,4-diacetoxyphenyl)-2-(4-nitrophenylseleno)ethanamin 
• 100945-21-9 3,4-Diacetoxy-α-(tert-butyloxycarbonylamino)acetophenon 
• 89525-03-1 <(S)-N-Acetylleucyl>-<(RS)-α-(dimethoxyphosphoryl)glycin-methylester> 
• 93894-91-8 <(S)-N-Acetylleucyl>-<(RS)-α-(dimethoxyphosphoryl)glycin> 
• 100945-24-2 acetic acid 2,3-diacetoxy-5-hydroxymethyl-phenyl ester 
• 100945-20-8 3,4-Diacetoxy-α-azidoacetophenon 
• 93862-78-3 <(S)-N-Acetylleucyl>-<(Z)-3,4,5-triacetoxy-α,β-didehydrophenylalanyl>-<(S)-6-brom-1-(tert-butyloxycarbonyl)tryptophan-tert-butylester> 
• 93862-73-8 (S)-6-Brom-1-(tert-butyloxycarbonyl)-N-(chloracetyl)tryptophan-tert-butylester 
• 93862-72-7 (Z)-3-<6-Brom-1-(tert-butyloxycarbonyl)-3-indolyl>-2-(chloracetylamino)acrylsaeure-tert-butylester 

Downstream Products

• 74144-16-4 Hexaaxetylcelenamid A 

Relevant articles and documents

Syntheses of Peptide Alkaloids, 11. - Amino Acids and Peptides, 51. - Dehydroamino Acids, 19. - Total Synthesis of Hexaacetylcelenamide A

The total synthesis of the linear peptide alkaloid hexaacetylcelenamide A (7) is described.Key steps are two condensation reactions with α-dialkylphosphoryl amino acid derivatives 10 to obtain the dehydroamino acid and dehydro peptide derivatives 14 and 17, respectively.