93930-23-5

Basic information

• Product Name: Benzene, 1,2,3-trimethoxy-5-(3-methyl-2-butenyl)-
• CAS NO: 93930-23-5
• Molecular Formula: C14H20O3
• Molecular Weight: 236.311
• Mol File: 93930-23-5.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzene, 1,2,3-trimethoxy-5-(3-methyl-2-butenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,2,3-trimethoxy-5-(3-methyl-2-butenyl)-(93930-23-5)
• EPA Substance Registry System: Benzene, 1,2,3-trimethoxy-5-(3-methyl-2-butenyl)-(93930-23-5)

Safety Data

• Hazardous Substances Data: 93930-23-5(Hazardous Substances Data)

Upstream product

• 20329-96-8 methyl 3,4,5-trimethoxycinnamate 
• 503-60-6 3,3-dimethyl-allyl chloride 
• 2675-79-8 1-bromo-3,4,5-trimethoxybenzene 
• 141550-13-2 4,4,5,5-tetramethyl-2-(3-methylbut-2-enyl)-1,3,2-dioxaborolane 
• 1191-16-8 3-methylbut-2-enyl acetate 
• 870-63-3 prenyl bromide 
• 182163-96-8 3,4,5-trimethoxyphenylboronic Acid 
• 53560-25-1 methyl 3-(3,4,5-trimethoxyphenyl)propionate 
• 20329-98-0 (E)-3,4,5-trimethoxy-cinnamic acid 
• 272124-87-5 [(E)-2-(3,4,5-Trimethoxy-phenyl)-vinyl]-phosphonic acid diethyl ester 
• 93930-22-4 2-methyl-4-(3,4,5-trimethoxyphenyl)butan-2-ol 

Relevant articles and documents

Ligand-controlled palladium-catalyzed regiodivergent suzuki-miyaura cross-coupling of allylboronates and aryl halides

An orthogonal set of catalyst systems has been developed for the Suzuki-Miyaura coupling of 3,3-disubstituted and 3-monosubstituted allylboronates with (hetero)aryl halides. These methods allow for the highly selective preparation of either the α- or the

Regioselective cross-coupling of allylboronic acid pinacol ester derivatives with aryl halides via Pd-PEPPSI-IPent

The cross-coupling reactions of allylboronic acid pinacol ester derivatives with aryl and heteroaryl halides occurred with high selectivity (>97%) at the α-carbon of the allylboron reagent in the presence of Pd-PEPPSI-IPent precatalyst and 5 M KOH in refluxing THF. In the case of trisubstituted allylboronates with different substituents on the olefin, minor olefin geometry isomerization was observed (E/Z & 80/20).

Heck reactions using aryldiazonium salts towards phosphonic derivatives

A facile synthesis of aryl vinylphosphonates has been based on Heck reaction of aryldiazonium salts bearing electrowithdrawing or donating groups with vinylphosphonates. A one-pot procedure consisting of Heck reaction and hydrogenation permits the clean f