940-54-5Relevant articles and documents
Dehydrogenation of 1-(diphenylphosphinoyl)-2-(N′-phenylhydrazino) ethane and N-butyl-N′-phenylhydrazine
Ovakimyan,Barsegyan,Pogosyan,Kikoyan,Indzhikyan
, p. 1757 - 1759 (2006)
Dehydrogenation of 1-(diphenylphosphinoyl)-2-hydrazino-substituted ethanes and N-butyl-N′-phenylhydrazine to the corresponding hydrazone derivatives is performed. Both reactions were established to involve predominantly, if not exclusively, an azo interme
Fast hydrazone reactants: Electronic and acid/base effects strongly influence rate at biological pH
Kool, Eric T.,Park, Do-Hyoung,Crisalli, Pete
supporting information, p. 17663 - 17666 (2014/01/06)
Kinetics studies with structurally varied aldehydes and ketones in aqueous buffer at pH 7.4 reveal that carbonyl compounds with neighboring acid/base groups form hydrazones at accelerated rates. Similarly, tests of a hydrazine with a neighboring carboxylic acid group show that it also reacts at an accelerated rate. Rate constants for the fastest carbonyl/hydrazine combinations are 2-20 M-1 s-1, which is faster than recent strain-promoted cycloaddition reactions.
Synthesis of 3-ethyl indole
Karaboyaci, Mustafa,Gülce, Ahmet
experimental part, p. 3295 - 3296 (2012/02/02)
In this study, it is planned to synthesize intermediates to get β-carboline alkaloids having effective bioligical activities. In this way, we tried to synthesize 3-ethyl indole as an intermediate from simple and cheap compounds to obtain the β-carboline s