94108-14-2Relevant academic research and scientific papers
Copper-catalyzed amination of aromatic halides with 2-N,N-dimethylaminoethanol as solvent
Lu, Zhikuan,Twieg, Robert J.,Huang, Songping D.
, p. 6289 - 6292 (2007/10/03)
A copper-catalyzed amination of aromatic halides under mild conditions using N,N-dimethylaminoethanol as solvent is described. We have studied this reaction in some detail varying the copper source, base, water content and other parameters including the scope of useful amine and aromatic halide structures. A variety of 4-halo-N,N-cycloalkylanilines and 2-N,N-cycloalkylaminothiophenes were synthesized for further elaboration into chromophores for optoelectronic applications.
High-pressure alkylation of bis(benzylidene)phenylenediamines
Agafonov,Dudin,Preobrazhenskii,Zhulin
, p. 273 - 275 (2007/10/03)
The reactions of alkyl chlorides with bisanils (obtained from o-, m-, and p-phenylenediamines) under high pressure (10 kbar) were studied. Depending on the structure of the starting diamines and the solvent nature, hydrolysis of the reaction mixtures gave
