94124-56-8Relevant academic research and scientific papers
SYNTHESIS OF α-HYDROXYDIMETHYLACETALS FROM NITROGEN HETEROCYCLIC KETONES USING HYPERVALENT IODINE OXIDATION
Moriarty, Robert M.,Prakash, Om,Thachet, Cyriac T.,Musallam, Hikmat A.
, p. 633 - 639 (2007/10/02)
The synthesis of various α-hydroxydimethylacetals (2a-2J) has been achieved by the oxidation of nitrogen containing heterocyclic ketones (1a-1j) using C6H5I(OAc)2-KOH-MeOH.The nmr and mass spectra of the acetals are discussed.
α-Hydroxydimethylacetal Formation From Aminoketones Using Hypervalent Iodine
Moriarty, Robert M.,Prakash, Om,Karalis, Pauline,Prakash, Indra
, p. 4745 - 4748 (2007/10/02)
Various β-aminoketones were converted into the α-hydroxydimethylacetal using either o-iodosylbenzoic acid or (diacetoxy) iodobenzene (KOH/CH3OH) without oxidation at 1 deg C, 2 deg C,or 3 deg C, amino groups or at sulfur in the case of a morpholino group.
