941282-79-7

Basic information

• Product Name: acetic acid 1-(2-hydroxy-ethoxy)-4-oxo-cyclohexa-2,5-dienylmethyl ester
• Synonyms: acetic acid 1-(2-hydroxy-ethoxy)-4-oxo-cyclohexa-2,5-dienylmethyl ester
• CAS NO: 941282-79-7
• Molecular Weight: 226.229
• Mol File: 941282-79-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: acetic acid 1-(2-hydroxy-ethoxy)-4-oxo-cyclohexa-2,5-dienylmethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: acetic acid 1-(2-hydroxy-ethoxy)-4-oxo-cyclohexa-2,5-dienylmethyl ester(941282-79-7)
• EPA Substance Registry System: acetic acid 1-(2-hydroxy-ethoxy)-4-oxo-cyclohexa-2,5-dienylmethyl ester(941282-79-7)

Safety Data

• Hazardous Substances Data: 941282-79-7(Hazardous Substances Data)

Upstream product

• 623-05-2 (4-hydroxyphenyl)methanol 
• 80767-12-0 4-hydroxybenzyl acetate 
• 107-21-1 ethylene glycol 

Downstream Products

• 881181-55-1 acetic acid 4-oxo-1-(2-oxoethoxy)cyclohexa-2,5-dienylmethyl ester 

Relevant articles and documents

Enantioselective synthesis of hydrobenzofuranones using an asymmetric desymmetrizing intramolecular stetter reaction of cyclohexadienones

A series of cyclohexadienones were synthesized by dearomatization of phenols followed by Dess - Martin oxidation. Asymmetric intramolecular Stetter reactions of these substrates provide hydrobenzofuranones in good to excellent yields and excellent stereoselectivities. Up to three stereocenters as well as a quaternary stereocenter are formed from polysubstituted substrates. A scale-up experiment demonstrates the utility of this transformation.