94194-07-7Relevant academic research and scientific papers
Stereoselective Synthesis of the B/C/D Ring Systems of Aphidicolane and Stemodane Diterpenes
Iwata, Chuzo,Morie, Toshiya,Maezaki, Naoyoshi,Shimamura, Hisafumi,Tanaka, Tetsuaki,Imanishi, Takeshi
, p. 930 - 932 (2007/10/02)
Diastereoisomeric tricyclo1,6>dodecane derivatives (3) and (4), which correspond to the B/C/D ring systems of aphidicolane and stemodane diterpenes, were selectively prepared from the common spirodienone (5) by means of facile regioselective C-C bond formation mediated by the neighbouring hydroxy group participation.
