942223-96-3Relevant academic research and scientific papers
N-donor ligands-directed coordination of Zn- azido complexes
Wang, Jing-Wen,Chen, Chen,Li, Yao-Ja,Luo, Yang-Hui,Sun, Bai-Wang
, p. 424 - 430 (2018)
Two zinc (II) pseudo-halide complexes [Zn(L1)(N3)2]n (1 L1: 1,2-diaminocyclohexane) and Zn(L2)2(N3)2 (2 L2: 4,5-dimethy-2-(pyridine-2-yl) imidazo
Luminescent zinc(II) and cadmium(II) complexes based on 2-(4,5-dimethyl-1H-imidazol-2-yl)pyridine and 2-(1-hydroxy-4,5-dimethyl-1H- imidazol-2-yl)pyridine
Bushuev,Selivanov,Pervukhina,Naumov,Rakhmanova,Sheludyakova,Tikhonov,Larionov
, (2012)
Complexes ZnL1Cl2, CdL1Cl2, ZnL2 1 Cl2 ·1.5H 2O, CdL2 1 Cl2 ·2H2O, CdL2 1 Clsu
Ligand field tuned spin crossover for an iron(II)-di(diamine) system
Luo, Yang-Hui,Chen, Lan,Wang, Jing-Wen,Wang, Ming-Xin,Zhang, Ya-Wen,Sun, Bai-Wang
, p. 8 - 11 (2016)
Investigation of spin-crossover in iron(II)-di(diamine) system, based on ligands L1, 4,5-dimethy-2-(pyridine-2-yl)imidazole, has been presented in this paper. The methyl group at the adjacent sites of the donor atoms in ligand L1 can generate the crossover situation for the iron(II) tris(diimine) system. While for the iron(II)-di(diamine) system with L1, the results are complicated: complex 1 {Fe(L1)2(SCN)2} displays paramagnetic behavior while 2 {Fe(L1)2(SeCN)2} is in crossover situation. The difference was attributed to the various ligand field strength of SCN- and SeCN-, which also resulted to the blue-shift of IR and Raman spectra, as well as red-shift and decrease in molar absorptivity of UV-Vis absorption spectrum.
Iridium complex as well as preparation method and application thereof
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Paragraph 0075; 0076; 0077; 0078, (2017/08/29)
The invention provides an iridium complex as well as a preparation method and an application thereof. The iridium complex is [(X)2Ir(L2)]Y, wherein X is a cyclometalated ligand, L2 is an auxiliary ligand and Y is a negative ion. With 2-(2,3,4,5-tetrafluor
