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94226-61-6

(2S,3S)-2-Dibenzylamino-3-hydroxy-3-phenyl-propionic acid methyl ester is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • (2S,3S)-2-Dibenzylamino-3-hydroxy-3-phenyl-propionic acid methyl ester

    Cas No: 94226-61-6

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  • 94226-61-6 Structure

  • Basic information

    1. Product Name: (2S,3S)-2-Dibenzylamino-3-hydroxy-3-phenyl-propionic acid methyl ester
    2. Synonyms:
    3. CAS NO:94226-61-6
    4. Molecular Formula:
    5. Molecular Weight: 375.467
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 94226-61-6.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (2S,3S)-2-Dibenzylamino-3-hydroxy-3-phenyl-propionic acid methyl ester(CAS DataBase Reference)
    10. NIST Chemistry Reference: (2S,3S)-2-Dibenzylamino-3-hydroxy-3-phenyl-propionic acid methyl ester(94226-61-6)
    11. EPA Substance Registry System: (2S,3S)-2-Dibenzylamino-3-hydroxy-3-phenyl-propionic acid methyl ester(94226-61-6)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 94226-61-6(Hazardous Substances Data)

94226-61-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 94226-61-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,4,2,2 and 6 respectively; the second part has 2 digits, 6 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 94226-61:
(7*9)+(6*4)+(5*2)+(4*2)+(3*6)+(2*6)+(1*1)=136
136 % 10 = 6
So 94226-61-6 is a valid CAS Registry Number.

94226-61-6Relevant articles and documents

DIBENZYLAMINOACETATES AS USEFUL SYNTHETIC EQUIVALENTS OF GLYCINE IN THEi SYNTHESIS OF α-AMINO-β-HYDROXYACIDS

Guanti, Giuseppe,Banfi, Luca,Narisano, Enrica,Scolastico, Carlo

, p. 3671 - 3684 (2007/10/02)

The stereochemical course of three new simple methodologies for the preparation of α-amino-β-hydroxyacids starting from dibenzylaminoacetates as synthetic equivalents of glycine is described.While the aldol-type condensation via lithium enolates gave results highly dependent on the aldehyde employed, producing in some cases diastereoselectivities up to 5:1 for the anti isomers, the acid-catalysed aldol condensation of silyl ketene acetals yielded predominantly syn adducts with selectivities from 5:1 to 32:1.Finally the acylation-reduction procedure gave the best results in terms of yields and stereoselectivities, affording syn isomers with excellent induction ( 13:1).

Alkylation and Condensation Reactions of N,N-Dibenzylglycine Esters: Synthesis of α-Amino Acid Derivatives

Gray, Brian D.,Jeffs, Peter W.

, p. 1329 - 1330 (2007/10/02)

Upon deprotonation N,N-dibenzylglycine esters undergo alkylation and condensation reactions at the α-carbon atom with various electrophiles.

DIASTEREOSELECTIVE SYNTHESIS OF α-AMINO-β-HYDROXYACIDS

Guanti, Giuseppe,Banfi, Luca,Narisano, Enrica,Scolastico, Carlo

, p. 4693 - 4696 (2007/10/02)

threo-α-Dibenzylamino-β-hydroxyesters (2) have been synthesised with high diastereoselectivity through the reduction of α-dibenzylamino-β-oxoesters (4) and then transformed into threo-α-amino-β-hydroxyacids.

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