94281-60-4Relevant academic research and scientific papers
Bis(phosphine)cobalt dialkyl complexes for directed catalytic alkene hydrogenation
Friedfeld, Max R.,Margulieux, Grant W.,Schaefer, Brian A.,Chirik, Paul J.
supporting information, p. 13178 - 13181 (2015/03/30)
Planar, low-spin cobalt(II) dialkyl complexes bearing bidentate phosphine ligands, (P - P)Co-(CH2SiMe3)2, are active for the hydrogenation of geminal and 1,2-disubstituted alkenes. Hydrogenation of more hindered internal and endocyclic trisubstituted alkenes was achieved through hydroxyl group activation, an approach that also enables directed hydrogenations to yield contrasteric isomers of cyclic alkanes.
Hydroalkoxylation of non-activated olefins catalysed by Lewis superacids in alcoholic solvents: an eco-friendly reaction
Lemechko, Pierre,Grau, Fanny,Antoniotti, Sylvain,Du?ach, Elisabet
, p. 5731 - 5734 (2008/02/09)
Lewis superacids such as tin(IV) triflate catalyse the intermolecular addition of primary alcohols to non-activated olefins under mild conditions.
